Gadolinium(III) sulfate is an inorganic compound with the chemical formula Gd2(SO4)3. The octahydrate forms colorless monoclinic crystals.
Structure and properties The octahydrate forms monoclinic crystals where Gd is coordinated by 4 oxygen atoms of crystal water and 4 oxygens of sulfate giving rise to a distorted square antiprism. It dehydrates in a two-step mechanism occurring between 130 and 306 °C, forming an amorphous solid. Recrystallization occurs between 380 and 411 °C, forming β-Gd2(SO4)3. A monotropic phase transition occurs at about 750 °C, forming α-Gd2(SO4)3 (space group: C2/c, a = 9.097 Å, b = 14.345 Å, c = 6.234 Å, β = 97.75°). Upon further heating, the oxysulfate (Gd2O2SO4) forms at 900 °C, which decomposes into cubic gadolinium oxide at 1200 °C.
Preparation The octahydrate can be prepared by treating gadolinium oxide with sulfuric acid.
Applications Gadolinium sulfate was introduced into the Super-Kamiokande neutrino observatory in order to improve its neutron detection efficiency. It is used in adiabatic demagnetization to achieve cryogenic temperatures.
References
Further reading Judge, W. D.; Ng, K. L.; Moldoveanu, G. A.; Kolliopoulos, G.; Papangelakis, V. G.; Azimi, G. (2023-04-01). "Solubilities of heavy rare earth sulfates in water (gadolinium to lutetium) and H2SO4 solutions (dysprosium)". Hydrometallurgy. 218 106054. doi:10.1016/j.hydromet.2023.106054. ISSN 0304-386X.



