When values of birefringence are very high, the property is termed giant birefringence which more generically is called giant optical anisotropy. Values for giant birefringence exceed 0.3. Much bigger numbers (over 2.0) are termed "colossal birefringence" which are achieved using nanostructures. Some oxides, for example borate or iodate can have high birefringence. Also compounds containing C=O bonds have higher levels. These include oxalates, squarates and cyanurates. One trade-off is with band gap. If the band gap is small, then the material is not transparent to visible light, but can be transparent for infrared. Chalgogenides may have high birefringence, but only in the infrared. Halide perovskites such as CsPbBrxCl3−x have fairly high birefringence that varies significantly in the optical spectrum. Polar organic π-conjugated molecules can have a strong response to electric fields and also form flat molecules that can stack to form anisotropic crystals with high birefringence. Some transition metal oxyhalides: MoOCl4, WOCl4, have birefringence in the giant category and MoO2Br2, WOBr4, NbOBr2, and NbOI2 are predicted to have birefringence over 0.6 at 1065 nm.
Applications Applications of materials with high birefringence include beam splitters, waveplates, optical circulators, and in some nonlinear optics systems.
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References
Extra reading Shen, Yaoguo; Xiong, Jiajia; Wu, Mengqing; Li, Mengcai; Zhou, Yingwu; Zhang, Yanjie (January 2026). "Enhancing Birefringence via a Planar-Conformation-Locking Strategy". Laser & Photonics Reviews. 20 (2) e01545. Bibcode:2026LPRv...2001545S. doi:10.1002/lpor.202501545. 2,2′-biquinoline dihydrochloride, dihydrobromide, or tetrahydroborate predicted 0.89, 0.85 and 0.82 @ 550 nm. Nguyen, Vivian; Chu, Chu; Sutherlin, Monique; Zhang, Bingbing; Wang, Jian (2026-01-21). "Synthesis, Crystal Growth, Linear, and Nonlinear Optical Properties of Water-Grown Giant Optical Anisotropic Thiocyanates ABi(SCN) 4 (A = Rb, Cs)". Crystal Growth & Design. 26 (2): 995–1002. Bibcode:2026CrGrD..26..995N. doi:10.1021/acs.cgd.5c01614. ISSN 1528-7483. predicted RbBi(SCN)4 birefringence 0.48@1064 and CsBi(SCN)4 0.66@546 nm Arif, Muhammad; Liu, Xu; Jia, Hangwei; Yang, Zhihua; Hou, Xueling; Pan, Shilie (2025). "Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution". Materials Horizons. 12 (10): 3538–3545. doi:10.1039/D4MH01790K. PMID 40007248. aminopyrazine sulfate derivatives Wu, Zhen-Cheng; Guo, Sheng-Ping (November 2025). "Research progress and future prospect of chalcogenides with large optical anisotropy". Coordination Chemistry Reviews. 542 216866. doi:10.1016/j.ccr.2025.216866. (review) Xu, A-Lan; Ran, Mao-Yin; Wu, Xin-Tao; Lin, Hua; Zhu, Qi-Long (October 2025). "Recent progress in structural design strategies of high-birefringence optical crystals". Coordination Chemistry Reviews. 540 216775. doi:10.1016/j.ccr.2025.216775. (review)
