Heap leaching is an industrial mining process used to extract precious metals, copper, uranium, and other compounds from ore using a series of chemical reactions that absorb specific minerals and re-separate them after their division from other earth materials. While similar to in situ mining, heap leach mining differs in that it places ore on a liner, then adds the chemicals via drip systems to the ore, whereas in situ mining lacks these liners and pulls pregnant solution up to obtain the minerals. Heap leaching is widely used in modern large-scale mining operations as it produces the desired concentrates at a lower cost compared to conventional processing methods such as flotation, agitation, and vat leaching. Additionally, dump leaching is an essential part of most copper mining operations and determines the quality grade of the produced material along with other factors Due to the profitability that the dump leaching has on the mining process, i.e. it can contribute substantially to the economic viability of the mining process, it is advantageous to include the results of the leaching operation in the economic overall project evaluation. The process has ancient origins; one of the classical methods for the manufacture of copperas (iron sulfate) was to heap up iron pyrite and collect the leachate from the heap, which was then boiled with iron to produce iron(II) sulfate.
Process
The mined ore is usually crushed into small chunks and heaped on an impermeable plastic or clay lined leach pad where it can be irrigated with a leach solution to dissolve the valuable metals. While sprinklers are occasionally used for irrigation, more often operations use drip irrigation to minimize evaporation, provide more uniform distribution of the leach solution, and avoid damaging the exposed mineral. The solution then percolates through the heap and leaches both the target and other minerals. This process, called the "leach cycle," generally takes from one or two months for simple oxide ores (e.g. most gold ores) to two years for nickel laterite ores. The leach solution containing the dissolved minerals is then collected, treated in a process plant to recover the target mineral and in some cases precipitate other minerals, and recycled to the heap after reagent levels are adjusted. Ultimate recovery of the target mineral can range from 30% of contained run-of-mine dump leaching sulfide copper ores to over 90% for the ores that are easiest to leach, some oxide gold ores. The essential questions to address during the process of the heap leaching are:
Can the investment of crushing the ore be justified by the potential increase in recovery and rate of recovery? How should the concentration of acid be altered over time in order to produce a solution that can be economically treated? How does the form of a heap affect the recovery and solution grade? Under any given set of circumstances, what type of recovery can be expected before the leach solution quality drops below a critical limit? What recovery (quantifiable measure) can be expected? In recent years, the addition of an agglomeration drum has improved on the heap leaching process by allowing for a more efficient leach. The rotary drum agglomerator works by taking the crushed ore fines and agglomerating them into more uniform particles. This makes it much easier for the leaching solution to percolate through the pile, making its way through the channels between particles. The addition of an agglomeration drum also has the added benefit of being able to pre-mix the leaching solution with the ore fines to achieve a more concentrated, homogeneous mixture and allow the leach to begin prior to the heap. Although heap leach design has made significant progress over the last few years through the use of new materials and improved analytical tools, industrial experience shows that there are significant benefits from extending the design process beyond the liner and into the rock pile itself. Characterization of the physical and hydraulic (hydrodynamic) properties of ore-for-leach focuses on the direct measurement of the key properties of the ore, namely:
The relationship between heap height and ore bulk density (density profile) The relationship between bulk density and percolation capacity (conductivity profile) The relationship between the bulk density, porosity and its components (micro and macro) The relationship between the moisture content and percolation capacity (conductivity curve) The relationship between the aforementioned parameters and the ore preparation practices (mining, crushing, agglomeration, curing, and method of placement) Theoretical and numerical analysis, and operational data show that these fundamental mechanisms are controlled by scale, dimensionality, and heterogeneity, all of which adversely affect the scalability of metallurgical and hydrodynamic properties from the lab to the field. The dismissal of these mechanisms can result in a number of practical and financial problems that will resonate throughout the life of the heap impacting the financial return of the operation. Through procedures that go beyond the commonly employed metallurgical testing and the integration of data gleaned through real time 3D monitoring, a more complete representative characterization of the physicochemical properties of the heap environment is obtained. This improved understanding results in a significantly higher degree of accuracy in terms of creating a truly representative sample of the environment within the heap. By adhering to the characterization identified above, a more comprehensive view of heap leach environments can be realized, allowing the industry to move away from the de facto black-box approach to a physicochemically inclusive industrial reactor model.
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