Hexachlorocyclohexa-2,5-dien-1-one, sometimes informally called hexachlorophenol (HCP), is an organochlorine compound. It can be prepared from phenol. Despite the informal name, the compound is not a phenol but is a ketone. The informal name may be derived from its method of preparation, which includes phenol as a reagent. It is a white solid with herbicidal properties.
Preparation and reactions HCP is normally produced by chlorination of phenol by chlorine in aqueous acetic acid. It can also be produced by alkaline hydrolysis of polychlorinated benzenes at high temperature and pressure, by conversion of diazonium salts of chlorinated anilines, or by chlorination of phenolsulfonic acids and benzenesulfonic acids followed by removal of the sulfonic acid group. The hydrolysis of HCP gives chloranil.
References
See also Pentachlorophenol Hexachlorobenzene




