Hiizu Iwamura (岩村 秀, Iwamura Hiizu; born 17 December 1934) is a Japanese chemist and Professor of Chemistry, Nihon University, as well as Professor Emeriti of the Institute for Molecular Science in Okazaki, the University of Tokyo, and Kyushu University in Japan.
Education 1957 B.S. Faculty of Science, The University of Tokyo 1962 D.Sci. in Chemistry, The University of Tokyo Thesis: Intramolecular Hydrogen Bonding between Hydroxy Group and π-Electron Systems (Supervisors: Professors Yoshiyuki Urushibara and Michinori Oki)
Academic experience 1962-1966 Assistant Professor, The University of Tokyo 1966-1969 Lecturer, The University of Tokyo 1967-1969 Research Associate, University of Wisconsin (with Prof Howard E. Zimmerman) 1970-1977 Associate Professor, The University of Tokyo November 1974-January 1975 DAAD Visiting Professor, University of Tübingen, Germany 1977-1988 Professor, Institute for Molecular Science, 1978-1987 Director of Division of Applied Molecular Science 1983-1985 Adjunct Professor, Faculty of Engineering, Nagoya University 1987-1995 Professor, The University of Tokyo November, 1987 Visiting Professor, University of Chicago 1994-1998 Professor, Kyushu University, 1995-1998 Director, Institute for Fundamental Research in Organic Chemistry, Kyushu University April–May, 1995 Visiting Professor, Louis Pasteur University, France 1998-2000 Professor, National Institution for Academic Degrees 2000-2005 Professor, University of the Air, 2001-2005 Director of Tokyo Bunkyo Study Center 2005-2010 Professor, Advanced Research Institute of Science and Humanity, Nihon University 2010–present Professor, College of Science and Technology, Nihon University
Professional activities 1979-1989 Associate and Titular Member, Commission on Organic Photochemistry, Division of Organic Chemistry, IUPAC 1992-1994 Member of the Board of Directors of the Chemical Society of Japan 1993-1994 Chairman, Kanto Section of the Chemical Society of Japan 1999-2012 Chairperson of the Committee for Validation and Examination for Degrees, National Institution for Academic Degrees and University Evaluation 2000-2005 Member of the Science Council of Japan 2005-2011 Corresponding Member of the Science Council of Japan March 2000-February 2001 President Elect, the Chemical Society of Japan March 2001-February 2002 President, The Chemical Society of Japan 2007-2008 The First President, Japan Union of Chemical Science and Technology
Journals involvement 1987-1996 Journal of Physical Organic Chemistry Editorial Board 1987-1992 New Journal of Chemistry, France, Advisory Board 1987-1999 Advances in Physical Organic Chemistry, Advisory Board 1988-2000 Chemical Reviews (American Chemical Society), Editorial Advisory Board
Chairmanship of conferences and symposia June 1982 Oji International Seminar on Chemistry of Weak Molecular Interactions in Aichi October 1992 International Conference on Chemistry and Physics of Molecule-Based Magnetic Materials in Tokyo 1990-1995 The Chemical Society of Japan Executive Committee for 1995-Chemical Congress of The Pacific Basin Societies in Honolulu 1995 The 6th Kyushu International Symposium on Physical Organic Chemistry 1995-2000 Vice-Chairman, 2000 Chemical Congress of the Pacific Basin Societies in Honolulu September 1996 The 1st Gordon Research Conference on Organic Structure and Properties in Fukuoka
Awards and honors 1963 The Chemical Society of Japan Award for Young Scientist November 1987 Julia and Edward Lee Lectureship from the University of Chicago 1992 The Chemical Society of Japan Award 1996 Purple Ribbon Medal of Japan (Shiju Hosho) 1998 Fujiwara Science Award 2001 Maria Sklodowska-Curie Medal from the Polish Chemical Society 2003 The Japan Academy Prize 2010 The Order of the Sacred Treasure
Major research interest and accomplishments Organic molecule-based magnets, Radical and carbene chemistry, Correlated internal rotation (molecular gears), Organic reactions in sub- and supercritical water. In 1984 he prepared hydrocarbon tri-carbene and tetra-carbene to demonstrate that their 2p-electron spins aligned in parallel and paramagnetic moments became greater than those of iron(III) and Gd(III) salts due to five 3d- and seven 4f-electron spins, respectively. The highest spin nona-carbene ever prepared had a S = 9 ground state (1993). Aminoxyl radicals and pyridylcarbenes were assembled into polymers by coordination with magnetic metal ions to give mixed metal-organic molecule-based magnets. They included a ferromagnet with the Curie temperature of 46 K (1996) and photomagnets where only the irradiated part become strongly magnetic (1997). Earlier he designed and prepared a whole series of di-(9-triptycyl)X (X=CH2, NH, O, SiH2, S) as molecular cog-wheels and demonstrated that they undergo almost free correlated internal rotation (disrotation) by various physical and chemical measurements. Since the rapid internal rotation of the cog-wheels does not get off the track, the di-9-triptycyl compounds carrying different benzene ring(s) gave isolable stereoisomers due to the phase of the label in spite of the rapid internal rotation (1980). More recently he developed a number of preparative organic reactions that proceed by way of aldol condensation and Michael addition in sub- or supercritical water in the absence of any added catalysts.
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