Hydrogen ozonide (HO3) is a radical molecule consisting of a hydrogen atom covalently bonded to an ozonide unit. It is possibly produced in the reaction of the hydroxyl radical with dioxygen: OH• + O2 → HO3•. It has been detected in a mass spectrometer experiment using HO+3 (protonated ozone) as precursor.
References
Extra reading Kalemos, Apostolos (1 February 2021). "Some ab initio thoughts on the bonding in O3H". Molecular Physics. 119 (3) e1804082. doi:10.1080/00268976.2020.1804082. S2CID 225486457. Fabian, W. M. F.; Kalcher, J.; Janoschek, R. (September 2005). "Stationary points on the energy hypersurface of the reaction O3 + H•→ [•O3H]* ⇆ O2 + •OH and thermodynamic functions of •O3H at G3MP2B3, CCSD(T)–CBS (W1U) and MR–ACPF–CBS levels of theory". Theoretical Chemistry Accounts. 114 (1–3): 182–188. doi:10.1007/s00214-005-0659-7. S2CID 100482298.



