Hydronium perchlorate is an inorganic chemical compound with the chemical formula [H3O]ClO4. It is an unusual salt due to it being a solid and stable hydronium salt. It consists of hydronium cations [H3O]+ and perchlorate anions ClO−4.
Production Hydronium perchlorate is produced by the reaction of anhydrous perchloric acid and water in a 1:1 molar ratio:
HClO4 + H2O → [H3O]+ClO−4 A more analytically reliable method was reported using the macrocyclic Schiff base of sodium 2,6-diformyl-4-methylphenolate and 2,6-diformyl-4-methylphenol as a chelating agent to sequester Cu(II): transmetallation of the macrocycle with copper(II) perchlorate yielded colorless crystals of hydronium perchlorate. It can also be produced by the reaction of anhydrous nitric acid and perchloric acid.
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