Iddingsite is a microcrystalline rock that is derived from alteration of olivine. It is usually studied as a mineral, and consists of a mixture of remnant olivine, clay minerals, iron oxides, and ferrihydrites. Debates over iddingsite's non-definite crystal structure caused it to be de-listed as an official mineral by the IMA; thus, it is properly referred to as a rock. Iddingsite forms from the weathering of basalt in the presence of liquid water and can be described as a phenocryst, i.e. it has macroscopically visible crystals in a fine-grained groundmass of a porphyritic rock. It is a pseudomorph that has a composition that is constantly transforming from the original olivine, passing through many stages of structural and chemical change to create a fully altered iddingsite. Because iddingsite is constantly transforming it does not have a definite structure or a definite chemical composition. The chemical formula for iddingsite has been approximated as MgO * Fe2O3 * 3SiO2 * 4 H2O where MgO can be substituted by CaO. The geologic occurrence of iddingsite is limited to extrusive or subvolcanic rocks that are formed by injection of magma near the surface. It is absent from deep-seated rocks and is found on meteorites. As it has been found on Martian meteorites, its ages have been calculated to obtain absolute ages when liquid water was at or near the surface of Mars. It was named after Joseph P. Iddings, an American petrologist.
Introduction Iddingsite is a pseudomorph, and during the alteration process the olivine crystals had their internal structure or chemical composition changed, although the external form has been preserved. This is not true for all phases of the alteration of olivine because the atomic arrangement becomes distorted and causes a non-definite structure to form. Iddingsite has a composition that is constantly transforming from the original olivine passing through many stages of structural and chemical change. Iddingsite has been a subject researched in recent years because of its presence in the Martian meteorites. The formation of iddingsite requires liquid water, giving scientists an estimate as to when there has been liquid water on Mars. Potassium-argon dating of the meteorite samples showed that Mars had water on its surface anywhere from 1300 Ma to 650 Ma ago.
Composition Iddingsite is a rock that lacks a definite chemical composition, so exact compositions cannot be calculated. An approximated composition for a hypothetical end product of iddingsite has been calculated as being SiO2 = 16%, Al2O3 = 8%, Fe2O3 = 62% and H2O = 14%. Throughout the alteration process of olivine, there is a decrease in SiO2, FeO and MgO and an increase in Al2O3 and H2O. The chemical process associated with the alteration consists of the addition of Fe2O3 and the removal of MgO (Gay and Le Maitre 1961). The chemical formula for iddingsite is approximated as MgO * Fe2O3 * 4 H2O where MgO can be substituted by CaO by a ratio of 1:4. There are also some trace constituents of Na2O and K2O that enter iddingsite as the alteration process progresses.
Geologic occurrence The geologic occurrence of Iddingsite is limited to extrusive or hypabyssal rocks, and it is absent from deep-seated rocks. Iddingsite is an epimagmatic mineral derived during the final cooling of lava in which it occurs from a reaction between gases, water and olivine. The formation of iddingsite is not dependent on the original composition of the olivine. It is however dependent on oxidation conditions, hydration and the magma from which iddingsite forms must be rich in water vapor. The alteration of olivine to iddingsite occurs in a highly oxidizing environment under low pressure and at intermediate temperatures. Temperature needed for the alteration process has to be above temperatures that could cause the olivine to solidify, but below temperatures that would cause structural reorganization.
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