Indium(III) selenide is a compound of indium and selenium. It has potential for use in photovoltaic devices and has been the subject of extensive research. The two most common phases, α and β, have a layered structure, while γ has a "defect wurtzite structure." In all, five polymorphs are known: α, β, γ, δ, κ. The α-β phase transition is accompanied by a change in electrical conductivity. The band gap of γ-In2Se3 is approximately 1.9 eV.
Preparation The method of production influences the polymorph generated. For example, thin films of pure γ-In2Se3 have been produced from trimethylindium (InMe3) and hydrogen selenide via MOCVD techniques.
3 H2Se + 2 In(CH3)3 → In2Se3 + 6 CH4 A conventional route entails heating the elements in a sealed tube:
3 Se + 2 In → In2Se3
See also Gallium(III) selenide Indium chalcogenides Nanoparticle
General references WebElements Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. doi:10.1016/C2009-0-30414-6. ISBN 978-0-08-037941-8.
Footnotes
External links Indium Selenide Nanoparticles Used In Solar Energy Conversion.



