The International Temperature Scale of 1990 (ITS-90) is an equipment calibration standard specified by the International Committee of Weights and Measures (CIPM) for making measurements on the Kelvin and Celsius temperature scales. It is an approximation of thermodynamic temperature that facilitates the comparability and compatibility of temperature measurements internationally. It defines fourteen calibration points ranging from 0.65 K to 1357.77 K (−272.50 °C to 1084.62 °C) and is subdivided into multiple temperature ranges which overlap in some instances. ITS-90 is the most recent of a series of International Temperature Scales adopted by the CIPM since 1927. Adopted at the 1989 General Conference on Weights and Measures, it supersedes the International Practical Temperature Scale of 1968 (amended edition of 1975) and the 1976 "Provisional 0.5 K to 30 K Temperature Scale". The CCT has also published several online guidebooks to aid realisations of the ITS-90. The lowest temperature covered by the ITS-90 is 0.65 K. In 2000, the temperature scale was extended further, to 0.9 mK, by the adoption of a supplemental scale, known as the Provisional Low Temperature Scale of 2000 (PLTS-2000). In 2019, the kelvin was redefined. However, the alteration was very slight compared to the ITS-90 uncertainties, and so the ITS-90 remains the recommended practical temperature scale without any significant changes. It is anticipated that the redefinition, combined with improvements in primary thermometry methods, will phase out reliance on the ITS-90 and the PLTS-2000 in the future.
Details The ITS-90 is designed to represent the thermodynamic (absolute) temperature scale (referencing absolute zero) as closely as possible throughout its range. Many different thermometer designs are required to cover the entire range. These include helium vapor pressure thermometers, helium gas thermometers, standard platinum resistance thermometers (known as SPRTs) and monochromatic radiation thermometers. Although the Kelvin and Celsius temperature scales were (until 2019) defined using the triple point of water (273.16 K or 0.01 °C), it is impractical to use this definition at temperatures that are very different from the triple point of water. Accordingly, ITS-90 uses numerous defined points, all of which are based on various thermodynamic equilibrium states of fourteen pure chemical elements and one compound (water). Most of the defined points are based on a phase transition; specifically the melting/freezing point of a pure chemical element. However, the deepest cryogenic points are based exclusively on the vapor pressure/temperature relationship of helium and its isotopes whereas the remainder of its cold points (those less than room temperature) are based on triple points. Examples of other defining points are the triple point of equilibrium hydrogen (13.8033 K or −259.3467 °C) and the freezing point of aluminium (933.473 K or 660.323 °C). The defining fixed points of the ITS-90 refer to pure chemical samples with specific isotopic compositions. As a consequence of this, the ITS-90 contains several equations to correct for temperature variations due to impurities and isotopic composition. Thermometers calibrated via the ITS-90 use complex mathematical formulas to interpolate between its defined points. The ITS-90 specifies rigorous control over variables to ensure reproducibility from lab to lab. For instance, the small effect that atmospheric pressure has upon the various melting points is compensated for (an effect that typically amounts to no more than half a millikelvin across the different altitudes and barometric pressures likely to be encountered). The standard also compensates for the pressure effect due to how deeply the temperature probe is immersed into the sample. The ITS-90 also draws a distinction between "freezing" and "melting" points. The distinction depends on whether heat is going into (melting) or out of (freezing) the sample when the measurement is made. Only gallium is measured at its melting points; all other metals with defining fixed points on the ITS-90 are measured at their freezing points. A practical effect of the ITS-90 is that the triple points and the freezing/melting points of its thirteen chemical elements are precisely known for all temperature measurements calibrated per the ITS-90 since these thirteen values are fixed by definition.
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