Iodine(I) fluorosulfonate is an inorganic compound of iodine, sulfur, fluorine, and oxygen with the chemical formula ISO3F. This is a monovalent compound of iodine from the group of fluorosulfonates.
Synthesis Like the other halofluorosulfonates, iodine(I) fluorosulfonate can be obtained from iodine and peroxydisulfuryl difluoride:
I2 + S2O6F2 → 2ISO3F
Chemical properties Reaction with iodine at 85 °C can convert iodine(I) fluorosulfate to triiodine fluorosulfonate.
I2 + ISO3F → I3SO3F When dissolved in carbon tetrachloride, iodine monochloride, peroxydisulfuryl difluoride, and phosgene are formed:
2ISO3F + CCl4 → 2ICl + S2O6F2 + COCl2 However, carbon dioxide can also be produced instead of phosgene:
4ISO3F + CCl4 → 4 ICl + 2 S2O6F2 + CO2
Physical properties The compound forms black crystals.
See also Bromine fluorosulfate Fluorine fluorosulfate Chlorine fluorosulfate Triiodine fluorosulfate
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