Ion

An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons (e.g. K+ (potassium ion)) while an anion is a negatively charged ion with more electrons than protons (e.g. Cl− (chloride ion) and OH− (hydroxide ion)). Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed monatomic ions, atomic ions or simple ions, while ions consisting of two or more atoms are termed polyatomic ions or molecular ions. The net charge of an ion is indicated as a superscript on the right. To indicate a +1 or −1 charge, only a + or − is written respectively, as seen in Na+ (sodium ion) and F− (fluoride ion). To indicate a more severe charge, the number of additional or missing electrons is supplied, as seen in O2−2 (peroxide, negatively charged, polyatomic) and He2+ (alpha particle, positively charged, monatomic). In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. Ions are also created by chemical interactions, such as the dissolution of a salt in liquids, or by other means, such as passing a direct current through a conducting solution, dissolving an anode via ionization.

History of discovery The word ion was coined from neuter present participle of Greek ἰέναι (ienai), meaning "to go". A cation is something that moves down (Greek: κάτω, kato, meaning "down") and an anion is something that moves up (Greek: ἄνω, ano, meaning "up"). They are so called because ions move toward the electrode of opposite charge. This term was introduced (after a suggestion by the English polymath William Whewell) by English physicist and chemist Michael Faraday in 1834 for the then-unknown species that goes from one electrode to the other through an aqueous medium. Faraday did not know the nature of these species, but he knew that since metals dissolved into and entered a solution at one electrode and new metal came forth from a solution at the other electrode; that some kind of substance has moved through the solution in a current. This conveys matter from one place to the other. In correspondence with Faraday, Whewell also coined the words anode and cathode, as well as anion and cation as ions that are attracted to the respective electrodes. Svante Arrhenius put forth, in his 1884 dissertation, the explanation of the fact that solid crystalline salts dissociate into paired charged particles when dissolved, for which he would win the 1903 Nobel Prize in Chemistry. Arrhenius' explanation was that in forming a solution, the salt dissociates into Faraday's ions, he proposed that ions formed even in the absence of an electric current.

Characteristics Ions in their gas-like state are highly reactive and will rapidly interact with ions of opposite charge to give neutral molecules or ionic salts. Ions are also produced in the liquid or solid state when salts interact with solvents (for example, water) to produce solvation shell around them. These solvated ions are more stable, for reasons involving a combination of energy and entropy changes as the ions move away from each other to interact with the liquid. These stabilized species are more commonly found in the environment at low temperatures. A common example is the ions present in seawater, which are derived from dissolved salts. As charged objects, ions are attracted to opposite electric charges (positive to negative, and vice versa) and repelled by like charges. When they move, their trajectories can be deflected by a magnetic field. Electrons, due to their smaller mass and thus larger space-filling properties as matter waves, determine the size of atoms and molecules that possess any electrons at all. Thus, anions (negatively charged ions) are larger than the parent molecule or atom, as the excess electron(s) repel each other and add to the physical size of the ion, because its size is determined by its electron cloud. Cations are smaller than the corresponding parent atom or molecule due to the smaller size of the electron cloud. One particular cation (that of hydrogen) contains no electrons, and thus consists of a single proton – much smaller than the parent hydrogen atom.

Anions and cations

The terms anion (−) and cation (+) refer to ions by the polarity of their net electric charge. Since the electric charge on a proton is equal in magnitude to the charge on an electron, the net electric charge on an ion (in units of elementary charge) is equal to the number of protons in the ion minus the number of electrons. An anion (−) ( ANN-eye-ən, from the Greek word ἄνω (ánō), meaning "up") is an ion with more electrons than protons, giving it a net negative charge (since electrons are negatively charged and protons are positively charged). A cation (+) ( KAT-eye-ən, from the Greek word κάτω (kátō), meaning "down") is an ion with fewer electrons than protons, giving it a net positive charge. There are additional names, though not formalized by the IUPAC, used for ions with charge of magnitude greater than 1. An ion with a −2 charge is known as a dianion; an ion with a +2 charge is known as a dication; an ion with a +3 charge is known as a trication, and so on. A zwitterion is a neutral molecule with positive and negative charges at different locations within that molecule. Cations and anions are measured by their ionic radius and they differ in relative size: "Cations are small, most of them less than 10−10 m (10−8 cm) in radius. But most anions are large, as is the most common Earth anion, oxygen. From this fact it is apparent that most of the space of a crystal is occupied by the anion and that the cations fit into the spaces between them." The terms anion and cation (for ions that respectively travel to the anode and cathode during electrolysis) were introduced by Michael Faraday in 1834 following his consultation with William Whewell.

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