Fluorine (9F) has 19 known isotopes ranging from 13F to 31F and two isomers (18mF and 26mF). Only fluorine-19 is stable and naturally occurring in more than trace quantities; therefore, fluorine is a monoisotopic and a mononuclidic element. The longest-lived radioisotope is 18F with a half-life of 109.734 minutes, followed by 17F with 64.37 seconds. These unstable isotopes participate in the CNO cycle within stars. All other fluorine isotopes have half-lives of less than 12 seconds, and most of those less than 1/2 second.
List of isotopes
Fluorine-18
Of the unstable nuclides of fluorine, 18F has the longest half-life, 109.734(8) min. It decays to 18O via β+ decay. For this reason 18F is a commercially important source of positrons. Its major value is in the production of the radiopharmaceutical fludeoxyglucose, used in positron emission tomography in medicine. Fluorine-18 is the second lightest unstable nuclide (after beryllium-8, with 4 protons and 4 neutrons) with equal numbers of protons and neutrons and lightest such with an odd atomic number, having 9 of each. (See also the parity discussion of nuclide stability.)
Fluorine-19 Fluorine-19 is the only stable isotope of fluorine. Its abundance is 100%; no other isotopes of fluorine exist in significant quantities. Its binding energy is 147801.3648(38) keV. Fluorine-19 is NMR-active with a spin of 1/2+, so it is used in fluorine-19 NMR spectroscopy.
Isomers Only two nuclear isomers (long-lived excited nuclear states), fluorine-18m and fluorine-26m, have been characterized. The half-life of 18mF before it undergoes isomeric transition is 162(7) nanoseconds. This is less than the decay half-life of any of the particle-bound fluorine radioisotope nuclear ground states. The half-life of 26mF is 2.2(1) milliseconds; it decays mainly to its ground state of 26F or (rarely, via beta-minus decay) to one of high excited states of 26Ne with delayed neutron emission.
See also Daughter products other than fluorine
Isotopes of neon Isotopes of oxygen
References
Sources Chisté, V.; Bé, M. M. (2011). "F-18" (PDF). In Bé, M. M.; Coursol, N.; Duchemin, B.; Lagoutine, F.; et al. (eds.). Table de radionucléides (Report). CEA (Commissariat à l'énergie atomique et aux énergies alternatives), LIST, LNE-LNHB (Laboratoire National Henri Becquerel/Commissariat à l'Energie Atomique). Archived from the original (PDF) on 11 August 2020. Retrieved 15 June 2011.
