Jacobus Henricus van 't Hoff Jr. (Dutch: [vɑn (ə)t ˈɦɔf]; 30 August 1852 – 1 March 1911) was a Dutch physical chemist. A highly influential theoretical chemist, in 1901 Van 't Hoff won the first Nobel Prize in Chemistry "[for his] discovery of the laws of chemical dynamics and osmotic pressure in solutions". His pioneering work helped found the modern theory of chemical affinity, chemical equilibrium, chemical kinetics, and chemical thermodynamics. In his 1874 pamphlet, Van 't Hoff formulated the theory of the tetrahedral carbon atom and laid the foundations of stereochemistry. In 1875, he predicted the correct structures of allenes and cumulenes as well as their axial chirality. He is also widely considered one of the three co-founders of physical chemistry as the discipline is known today. The Zeitschrift für physikalische Chemie (Journal of Physical Chemistry) was founded in 1887 by Van ’t Hoff, Svante Arrhenius and Wilhelm Ostwald, at Leipzig University as the first dedicated scientific journal for the discipline.
Biography The third of seven children, Van 't Hoff was born in Rotterdam, Netherlands, 30 August 1852. His father was Jacobus Henricus van 't Hoff Sr., a physician, and his mother was Alida Kolff van 't Hoff. From a young age, he was interested in science and nature, and frequently took part in botanical excursions. In his early school years, he showed a strong interest in poetry and philosophy. He considered Lord Byron to be his idol. Against the wishes of his father, Van 't Hoff chose to study chemistry. First, he enrolled at Delft University of Technology in September 1869, and studied until 1871, when he passed his final exam on 8 July and obtained a degree of chemical technologist. He passed all his courses in two years, although the time assigned to study was three years. Then he enrolled at University of Leiden to study chemistry. He then studied in Bonn, Germany, with August Kekulé and in Paris with Adolphe Wurtz. He received his doctorate under Eduard Mulder at the University of Utrecht in 1874. In 1878, Van 't Hoff married Johanna Francina Mees. They had two daughters, Johanna Francina (1880–1964) and Aleida Jacoba (1882–1971), and two sons, Jacobus Henricus van 't Hoff III (1883–1943) and Govert Jacob (1889–1918). Van 't Hoff died at the age of 58, on 1 March 1911, at Steglitz, near Berlin, of tuberculosis.
Career
Organic chemistry Van 't Hoff earned his earliest reputation in the field of organic chemistry. In 1874, he accounted for the phenomenon of optical activity by assuming that the chemical bonds between carbon atoms and their neighbors were directed towards the corners of a regular tetrahedron. This three-dimensional structure accounted for the isomers found in nature. He shares credit for this with the French chemist Joseph Le Bel, who independently came up with the same idea. Three months before his doctoral degree was awarded, Van 't Hoff published this theory, which today is regarded as the foundation of stereochemistry, first in a Dutch pamphlet in the fall of 1874, and then in the following May in a small French book entitled La chimie dans l'espace. A German translation appeared in 1877, at a time when the only job Van 't Hoff could find was at the Veterinary School in Utrecht. In these early years his theory was largely ignored by the scientific community, and was sharply criticized by one prominent chemist, Hermann Kolbe. Kolbe wrote:
"A Dr. J. H. van 't Hoff of the Veterinary School at Utrecht has no liking, apparently, for exact chemical investigation. He has considered it more convenient to mount Pegasus (apparently borrowed from the Veterinary School) and to proclaim in his ‘La chimie dans l’espace’ how, in his bold flight to the top of the chemical Parnassus, the atoms appeared to him to be arranged in cosmic space." However, by about 1880, support for Van 't Hoff's theory by such important chemists as Johannes Wislicenus and Viktor Meyer brought recognition.
Physical chemistry In 1884, Van 't Hoff published his research on chemical kinetics, titled Études de Dynamique chimique ("Studies in Chemical Dynamics"), in which he described a new method for determining the order of a reaction using graphics and applied the laws of thermodynamics to chemical equilibria. He also introduced the modern concept of chemical affinity. In 1886, he showed a similarity between the behaviour of dilute solutions and gases. In 1887, he and German chemist Wilhelm Ostwald founded an influential scientific magazine named Zeitschrift für physikalische Chemie ("Journal of Physical Chemistry"). He worked on Svante Arrhenius's theory of the dissociation of electrolytes and in 1889 provided physical justification for the Arrhenius equation. In 1896, he became a professor at the Prussian Academy of Sciences in Berlin. His studies of the salt deposits at Stassfurt were an important contribution to Prussia's chemical industry.
Van 't Hoff became a lecturer in chemistry and physics at the Veterinary College in Utrecht. He then worked as a professor of chemistry, mineralogy, and geology at the University of Amsterdam for almost 18 years before eventually becoming the chairman of the chemistry department. In 1896, van 't Hoff moved to Germany, where he finished his career at the University of Berlin in 1911. In 1901, he received the first Nobel Prize in Chemistry for his work with solutions. His work showed that very dilute solutions follow mathematical laws that closely resemble the laws describing the behavior of gases.
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