In atomic physics, the Landé interval rule states that, due to weak angular momentum coupling (either spin-orbit or spin-spin coupling), the energy splitting between successive sub-levels are proportional to the total angular momentum quantum number (J or F) of the sub-level with the larger of their total angular momentum value (J or F).
Background The rule assumes the Russell–Saunders coupling and that interactions between spin magnetic moments can be ignored. The latter is an incorrect assumption for light atoms. As a result of this, the rule is optimally followed by atoms with medium atomic numbers. The rule was first stated in 1923 by German-American physicist Alfred Landé.
Derivation As an example, consider an atom with two valence electrons and their fine structures in the LS-coupling scheme. We will derive heuristically the interval rule for the LS-coupling scheme and will remark on the similarity that leads to the interval rule for the hyperfine structure. The interactions between electrons couple their orbital and spin angular momentums. Let's denote the spin and orbital angular momentum as s {\displaystyle \mathbf {s} } and l {\displaystyle \mathbf {l} } for each electrons. Thus, the total orbital angular momentum is L = l 1 + l 2 {\displaystyle \mathbf {L} =\mathbf {l} _{1}+\mathbf {l} _{2}} and total spin momentum is S = s 1 + s 2 {\displaystyle \mathbf {S} =\mathbf {s} _{1}+\mathbf {s} _{2}} . Then the coupling in the LS-scheme gives rise to a Hamiltonian:
H s − o = β 1 s 1 ⋅ l 1 + β 2 s 2 ⋅ l 2 {\displaystyle H_{\mathrm {s} -\mathrm {o} }=\beta _{1}\mathbf {s} _{1}\cdot \mathbf {l} _{1}+\beta _{2}\mathbf {s} _{2}\cdot \mathbf {l} _{2}}
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