Landau–Placzek ratio is a ratio of the integrated intensity of Rayleigh scattering to the combined integrated intensity of Brillouin scattering of a triplet frequency spectrum of light scattered by homogenous liquids or gases. The triplet consists of two frequency shifted Brillouin scattering and a central unshifted Rayleigh scattering line split. The triplet structure was explained by Lev Landau and George Placzek in 1934 in a short publication, summarizing major results of their analysis. Landau and Placzek noted in their short paper that a more detailed discussion will be published later although that paper does not seem to have been published. However, a detailed discussion is provided in Lev Landau and Evgeny Lifshitz's book. The Landau–Placzek ratio is defined as
R L P = I c 2 I B {\displaystyle R_{LP}={\frac {I_{c}}{2I_{B}}}}
where
I c {\displaystyle I_{c}} is the integral intensity of central Rayleigh peak
I B {\displaystyle I_{B}} is the integral intensity of Brillouin peak. The Landau–Placzek formula provides an approximate theoretical prediction for the Landau–Placzek ratio,
R L P = c p − c v c v {\displaystyle R_{LP}={\frac {c_{p}-c_{v}}{c_{v}}}}
where
c p {\displaystyle c_{p}} is the specific heat at constant pressure
c v {\displaystyle c_{v}} is the specific heat at constant volume.
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