Lanthanum disilicide is a binary inorganic compound of lanthanum metal and silicon with the formula LaSi2. Many other lanthanum silicides are known.
Synthesis Combine silicon and lanthanum powders, compress the mixture into solid blocks, and melt under vacuum conditions. React lanthanum, silicon, and mercury in a quartz tube at 450 °C for 10–12 hours. Subsequently, eliminate surplus mercury through distillation, followed by annealing the resultant material at 450–600 °C.
Physical properties Lanthanum disilicide forms gray crystals. LaSi2 can exist in two crystal structures: tetragonal (α-GdSi2 type) and orthorhombic (α-ThSi2 type). The compound is known for its metallic behavior and various applications.
Chemical properties LaSi2 reacts with hydrochloric acid and hydrofluoric acid; insoluble in water.
Uses The LaSi2-powder is characterized by high electrical resistivity, minimal thermal expansion, and outstanding thermal stability. These properties make it potentially useful for applications in electric heating devices, high-temperature sensors, refractory ceramics, thermal tools, and materials designed for efficient heat conduction.
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