Lanthanum hydroxide is La(OH)3, a hydroxide of the rare-earth element lanthanum.
Synthesis Lanthanum hydroxide can be obtained by adding an alkali such as ammonia to aqueous solutions of lanthanum salts such as lanthanum nitrate. This produces a gel-like precipitate that can then be dried in air.
La(NO3)3 + 3 NH4OH → La(OH)3 + 3 NH4NO3 Alternatively, it can be produced by hydration reaction (addition of water) to lanthanum oxide.
La2O3 + 3 H2O → 2 La(OH)3
Characteristics Lanthanum hydroxide does not react much with alkaline substances, however is slightly soluble in acidic solution. In temperatures above 330 °C it decomposes into lanthanum oxide hydroxide (LaOOH), which upon further heating decomposes into lanthanum oxide (La2O3):
La(OH)3 → − H 2 O 330 o C {\displaystyle \mathrm {{\xrightarrow[{-H_{2}O}]{330\ ^{o}C}}\ } } LaOOH 2 LaOOH → − H 2 O Δ {\displaystyle \mathrm {{\xrightarrow[{-H_{2}O}]{\Delta }}\ } } La2O3 Lanthanum hydroxide crystallizes in the hexagonal crystal system. Each lanthanum ion in the crystal structure is surrounded by nine hydroxide ions in a tricapped trigonal prism.
References
External links "Lanthanum - Element information, properties and uses - Periodic Table". rsc.org. External MSDS 1 External MSDS 2 Lanthanum Oxide MSDS




