Lanthanum nitride is a binary inorganic compound of lanthanum and nitride with the chemical formula LaN.
Preparation Lanthanum nitride can be prepared from the reaction of nitrogen and lanthanum trihydride:
2 LaH3 + N2 → 2 LaN + 3 H2 It can also be prepared from the reaction of ammonia and lanthanum trihydride:
LaH3 + NH3 → LaN + 3 H2 The reaction of nitrogen and lanthanum amalgam can also work:
La + ½ N2 → LaN (1000 - 1400 °C) Ammonia is more reactive than N2 gas, so the synthesis works at lower temperatures:
La + NH3 → LaN + 1.5 H2 (700 °C)
Physical properties Lanthanum nitride forms black powder that is insoluble in water. Their crystals are of the cubic system with the Fm3m space group. It is paramagnetic.
Chemical properties Lanthanum nitride reacts with water and moisture from the air:
LaN + 3 H2O → La(OH)3 + NH3 It reacts with acids:
LaN + 4 HCl → LaCl3 + NH4Cl
Uses LaN is used as a LED material, magnetic material, and in semiconductors, refractory materials, dyes, and catalysts.
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