Lanthanum tetraboride is a binary inorganic compound of lanthanum and boron with the chemical formula LaB4. The compound forms a gray to black crystalline solid and demonstrates metallic conductivity.
Properties Lanthanum tetraboride is a refractory, high-hardness inorganic compound crystallizing in the tetragonal crystal system, space group P4/mbm. The arrangement of atoms is the same as in the tetraborides of cerium, thorium and uranium (CeB4, ThB4, UB4) LaB4 is distinct from the more common lanthanum hexaboride LaB6 but shares high-temperature stability, with its boron sublattices containing structural elements of both diborides and hexaborides. The compound undergoes a series of phase transitions under high pressure.
Synthesis Lanthanum tetraboride can be prepared by the reduction of lanthanum oxide by boron carbide under vacuum:
La2O3 + 2 B4C + С → 2 LaB4 + 3 CO Another method involves heating lanthanum metal and boron at 1300 °C under vacuum.
Uses The compound is generally a subject of materials science research. Also it is especially suitable for high-temperature applications.
References
Further reading Bolgar, A. S.; Muratov, V. B.; Meleshevich, K. A.; Khorpyakov, O. T. (1 November 1990). "Thermodynamic parameters for lanthanum tetraboride over a wide temperature range". Soviet Powder Metallurgy and Metal Ceramics. 29 (11): 917–920. doi:10.1007/BF00794028. ISSN 1573-9066. Retrieved 6 May 2026.
