Lenthionine is an organosulfur compound with the formula (CH2)2S5. The compound consists of a 1,4-C2S5 ring (pentathiepane). Lenthionine is a major component of the organosulfur compounds found in shiitake mushrooms (Lentinula edodes), onions, and garlic, and it is partly responsible for their flavor. The mechanism of its formation is unclear, but it likely involves the enzyme C–S lyase.
Preparation Lenthionine has been prepared by treating dichloromethane with polysulfide solutions.
Further reading Liu, Qin; Cui, Xiao; Song, Zhibo; Kong, Weiwei; Kang, Yuanchun; Kong, Weili; Ng, Tzi Bun (2021). "Coating shiitake mushrooms (Lentinus edodes) with a polysaccharide from Oudemansiella radicata improves product quality and flavor during postharvest storage". Food Chemistry. 352 129357. doi:10.1016/j.foodchem.2021.129357. PMID 33714165. Wratten, Stephen J.; Faulkner, D. John (1976). "Cyclic polysulfides from the red alga Chondria californica". The Journal of Organic Chemistry. 41 (14): 2465–2467. doi:10.1021/jo00876a025. PMID 932864.
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