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chemistry

MOF-5

MOF-5 is a chemistry topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand MOF-5 rather than just read about it. In short: MOF-5 or IRMOF-1 is a cubic metal–organic framework compound with the formula Zn4O(BDC)3, where BDC2− = 1,4-benzodicarboxylate (MOF-5). It was first synthesized in the lab of Omar M.

MOF-5 — main illustration
MOF-5 — illustration

Key takeaways

  • MOF-5 belongs to chemistry; place it in that map before memorising details.
  • Learn the definition first, then one example that makes the definition concrete.
  • Connect MOF-5 to a quantity you can measure, compute or draw — that is where exam questions come from.
  • Reproduce the core statement of MOF-5 from memory before moving on to harder problems.

Reference excerpt

MOF-5 or IRMOF-1 is a cubic metal–organic framework compound with the formula Zn4O(BDC)3, where BDC2− = 1,4-benzodicarboxylate (MOF-5). It was first synthesized in the lab of Omar M. Yaghi. MOF-5 is notable for exhibiting one of the highest surface area to volume ratios among metal–organic frameworks, at 2200 m2/cm3. Additionally, it was the first metal–organic framework studied for hydrogen gas storage. Yaghi's work on MOF-5 is partially responsible for his 2025 Nobel Prize in Chemistry.

References

Illustrations

MOF-5: Crystal structure of MOF-5.                                                            A JSmol visualization can be found here
Crystal structure of MOF-5. A JSmol visualization can be found here

Worked examples

Example 1 — a first encounter with MOF-5

Start with the simplest possible case. Write down what MOF-5 claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In chemistry, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to MOF-5 before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about MOF-5 ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of MOF-5

In research
MOF-5 appears in chemistry research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry
Engineering practice reuses MOF-5 in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom
MOF-5 is common in secondary-school and first-year university syllabi. It links to neighbouring topics Materials science stubs, Metal-organic frameworks, Zinc complexes, so understanding it makes those chapters shorter.
In everyday life
Look for MOF-5 outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.

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How to study MOF-5 in 20 minutes

  1. Read the reference excerpt below once, without taking notes.
  2. Close the page and write down what MOF-5 means in your own words.
  3. Compare your version with the excerpt and mark what you missed.
  4. Work through the three examples above with pen and paper.
  5. Explain MOF-5 out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is MOF-5 in simple terms?

MOF-5 or IRMOF-1 is a cubic metal–organic framework compound with the formula Zn4O(BDC)3, where BDC2− = 1,4-benzodicarboxylate (MOF-5). It was first synthesized in the lab of Omar M.

Why does MOF-5 matter?

Because it connects several chemistry ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study MOF-5?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on MOF-5.

Tags

  • Materials science stubs
  • Metal-organic frameworks
  • Zinc complexes

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