Magnesite is a mineral with the chemical formula MgCO3 (magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts. Magnesite occurs naturally in both cryptocrystalline and crystalline forms depending on the conditions of formation. Magnesite is used in the production of magnesium oxide for the refractory lining of kilns and furnaces, as well as artistically in jewelry and sculpture. Since it may be formed by carbonation of magnesium serpentine, there have also been efforts to use magnesite for carbon sequestration.
Occurrence Magnesite occurs as veins in and an alteration product of ultramafic rocks, serpentinite and other magnesium rich rock types in both contact and regional metamorphic terrains. These magnesites are often cryptocrystalline and contain silica in the form of opal or chert.
Magnesite is also present within the regolith above ultramafic rocks as a secondary carbonate within soil and subsoil, where it is deposited as a consequence of dissolution of magnesium-bearing minerals by carbon dioxide in groundwaters. Crystalline and cryptocrystalline magnesites have very different mineral structures. While crystalline magnesite has a well developed crystal structure, the cryptocrystalline magnesite is amorphous- mostly aggregate of fine grains.
Formation Magnesite can be formed via talc carbonate metasomatism of peridotite and other ultramafic rocks. Magnesite is formed via carbonation of olivine in the presence of water and carbon dioxide at elevated temperatures and high pressures typical of the greenschist facies. Magnesite can also be formed via the carbonation of magnesium serpentine (lizardite) via the following reaction:
2 Mg3Si2O5(OH)4 + 3 CO2 → Mg3Si4O10(OH)2 + 3 MgCO3 + 3 H2O However, when performing this reaction in the laboratory, the trihydrated form of magnesium carbonate (nesquehonite) will form at room temperature. This very observation led to the postulation of a "dehydration barrier" being involved in the low-temperature formation of anhydrous magnesium carbonate. Laboratory experiments with formamide, a liquid resembling water, have shown how no such dehydration barrier can be involved. The fundamental difficulty to nucleate anhydrous magnesium carbonate remains when using this non-aqueous solution. Not cation dehydration, but rather the spatial configuration of carbonate anions creates the barrier in the low-temperature nucleation of magnesite. Magnesite has been found in modern sediments, caves and soils. Its low-temperature (around 40 °C [104 °F]) formation is known to require alternations between precipitation and dissolution intervals. The low-temperature formation of magnesite might well be of significance toward large-scale carbon sequestration. A major step forward toward the industrial production of magnesite at atmospheric pressure and a temperature of 316 K was described by Vandeginste. In those experiments small additions of hydrochloric acid alternated periodically with additions of sodium carbonate solution. Also new in these experiments was the very short duration of only a few hours for the alternating dissolution and precipitation cycles. Magnesite was detected in meteorite ALH84001 and on planet Mars itself. Magnesite was identified on Mars using infrared spectroscopy from satellite orbit. Near Jezero Crater, Mg-carbonates have been detected and reported to have formed in lacustrine environment prevailing there. Controversy still exists over the temperature of formation of these carbonates. Low-temperature formation has been suggested for the magnesite from the Mars-derived ALH84001 meteorite. Magnesium-rich olivine (forsterite) favors production of magnesite from peridotite. Iron-rich olivine (fayalite) favors production of magnetite-magnesite-silica compositions. Magnesite can also be formed by way of metasomatism in skarn deposits, in dolomitic limestones, associated with wollastonite, periclase, and talc. Resistant to high temperature and able to withstand high pressure, magnesite has been proposed to be one of the major carbonate bearing phase in Earth's mantle and possible carriers for deep carbon reservoirs. For similar reason, it is found in metamorphosed peridotite rocks in Central Alps, Switzerland and high pressure eclogitic rocks from Tianshan, China. Magnesite can also precipitate in lakes in presence of bacteria either as hydrous Mg-carbonates or magnesite.
Isotopic evidence
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