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Melilite

Melilite is a earth science topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand Melilite rather than just read about it. In short: Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite.

Melilite — main illustration
Melilite — illustration

Key takeaways

  • Melilite belongs to earth science; place it in that map before memorising details.
  • Learn the definition first, then one example that makes the definition concrete.
  • Connect Melilite to a quantity you can measure, compute or draw — that is where exam questions come from.
  • Reproduce the core statement of Melilite from memory before moving on to harder problems.

Reference excerpt

Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is (Ca,Na)2(Al,Mg,Fe2+)[(Al,Si)SiO7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series. Minerals of the melilite group are sorosilicates. They have the same basic structure, of general formula A2B(T2O7). The melilite structure consist of pairs of fused TO4, where T may be Si, Al, B, in bow-tie form. Sharing one corner, the formula of the pair is T2O7. These bow-ties are linked together into sheets by the B cations. The sheets are held together by the A cations, most commonly calcium and sodium. Aluminium may sit on either the T or the B site. Minerals with the melilite structure may show a cleavage parallel to the (001) crystallographic directions and may show weaker cleavage perpendicular to this, in the {110} directions. Melilite is tetragonal. The important endmembers of common melilite are åkermanite Ca2Mg(Si2O7) and gehlenite Ca2Al[AlSiO7]. Many melilites also contain appreciable iron and sodium. Some other compositions with the melilite structure include: alumoåkermanite (Ca,Na)2(Al,Mg,Fe2+)(Si2O7), okayamalite Ca2B[BSiO7], gugiaite Ca2Be[Si2O7], hardystonite Ca2Zn[Si2O7], barylite BaBe2[Si2O7], andremeyerite BaFe2+2[Si2O7]. Some structures formed by replacing one oxygen by F or OH: leucophanite (Ca,Na)2(Be,Al)[Si2O6(F,OH)], jeffreyite (Ca,Na)2(Be,Al)[Si2O6(O,OH)], and meliphanite (Ca,Na)2(Be,Al)[Si2O6(OH,F)]. New members of this mineral group were artificially grown and became intensively studied due to their multiferroic property, i.e., they simultaneously show ferroelectric and magnetic ordering at low temperatures. This gives rise to peculiar optical properties, for example Ba2Co(Ge2O7) shows giant directional dichroism (different absorption for counter-propagating light beams) and hosts magnetically switchable chirality.

Occurrences Melilite with compositions dominated by the endmembers akermanite and gehlenite is widely distributed but uncommon. It occurs in metamorphic and igneous rocks and in meteorites. Typical metamorphic occurrences are in high-temperature metamorphosed impure limestones. For instance, melilite occurs in some high-temperature skarns. Melilite also occurs in unusual silica-undersaturated igneous rocks. Some of these rocks appear to have formed by reaction of magmas with limestone. Other igneous rocks containing melilite crystallize from magma derived from the Earth's mantle and apparently uncontaminated by the Earth's crust. The presence of melilite is an essential constituent in some rare igneous rocks, such as olivine melilitite. Extremely rare igneous rocks contain as much as 70% melilite, together with minerals such as pyroxene and perovskite. Melilite is a constituent of some calcium–aluminium-rich inclusions in chondritic meteorites. Isotope ratios of magnesium and some other elements in these inclusions are of great importance in deducing processes that formed the Solar System.

Melilitite is a volcanic rock composed of over 90% melilite, with small amounts of olivine, clinopyroxene, and perovskite. The intrusive equivalent is melilitolite. When pyroxene is absent from the rock, and the accessory minerals are olivine, magnetite, leucite, kalsilite, nepheline, and perovskite, the rock is sometimes called katungite. However, more modern classification schemes avoid the term katungite and describe the rock instead as (for example) kalsilite-leucite-olivine melilitite, depending on the most abundant accessory minerals. Alnöite is a melilitite devoid of glass or feldspathoids with melilite in its groundmass.

See also

Classification of minerals List of minerals

References

Deer, W.A., Howie, R.A., and Zussman, J. (1986) Disilicates and Ring Silicates, Rock-forming minerals 1B, 2nd Ed., New York : John Wiley & Sons, ISBN 0-582-46521-4

External links

Zinner, E. "Using Aluminum-26 as a Clock for Early Solar System Events." PSR Discoveries. September 2002 Accessed December, 2007 Optical properties of multiferroics

Illustrations

Melilite illustration
Melilite: A view down onto the sheets of the A2B(T2O7) melilite structure. The A sites are yellow spheres, the B sites are pale orange tetrahedra, and the T sites are blue tetrahedra. Oxygen atoms (not shown) are on the corners of the tetrahedra.
A view down onto the sheets of the A2B(T2O7) melilite structure. The A sites are yellow spheres, the B sites are pale orange tetrahedra, and the T sites are blue tetrahedra. Oxygen atoms (not shown) are on the corners of the tetrahedra.
Melilite: Crossed polarized light image of melilite in Moiliili lava flow, Moiliili Quarry, Honolulu, O‘ahu, Hawai‘i surrounded by matrix of granular nepheline and volcanic glass. This rock (nepheline-melilite basalt) was erupted during rejuvenated volcanism on O‘ahu.
Crossed polarized light image of melilite in Moiliili lava flow, Moiliili Quarry, Honolulu, O‘ahu, Hawai‘i surrounded by matrix of granular nepheline and volcanic glass. This rock (nepheline-melilite basalt) was erupted during rejuvenated volcanism on O‘ahu.

Worked examples

Example 1 — a first encounter with Melilite

Start with the simplest possible case. Write down what Melilite claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In earth science, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to Melilite before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about Melilite ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of Melilite

In research
Melilite appears in earth science research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry
Engineering practice reuses Melilite in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom
Melilite is common in secondary-school and first-year university syllabi. It links to neighbouring topics Aluminium minerals, Calcium minerals, Iron(II) minerals, so understanding it makes those chapters shorter.
In everyday life
Look for Melilite outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.

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How to study Melilite in 20 minutes

  1. Read the reference excerpt below once, without taking notes.
  2. Close the page and write down what Melilite means in your own words.
  3. Compare your version with the excerpt and mark what you missed.
  4. Work through the three examples above with pen and paper.
  5. Explain Melilite out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is Melilite in simple terms?

Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite.

Why does Melilite matter?

Because it connects several earth science ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study Melilite?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on Melilite.

Tags

  • Aluminium minerals
  • Calcium minerals
  • Iron(II) minerals
  • Magnesium minerals
  • Minerals in space group 113
  • Sorosilicates
  • Tetragonal minerals

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