Merrillite is a calcium phosphate mineral with the chemical formula Ca9NaMg(PO4)7. It is an anhydrous, sodium-rich member of the merrillite group of minerals.
Mineral species, sub-group and group Merrillite is a distinct mineral species but it also gives its name to a set of similar minerals, which together form the merrillite sub-group of minerals. The merrillite sub-group and the whitlockite sub-group together form the merrillite group of minerals.
Merrillite Group Merrillite Sub-group Ferromerrillite Keplerite Matyhite Merrillite Whitlockite Sub-group Hedegaardite Strontiowhitlockite Whitlockite Wopmayite In September 2022 the discovery of another merrillite group mineral, changesite–(Y), was announced, but, as of September 2022, it is not yet clear where this new mineral sits in the merrillite group hierarchy.
Discovery and naming Merrillite is named after George P. Merrill (1854–1929) of the Smithsonian Institution. In 1915, Merrill had described the mineral from four meteorites: Alfianello, Dhurmsala, Pultusk and Rich Mountain. Merrillite has also been reported from the Renchen meteorite (a well-documented fall that occurred on 10 July 2018 at 21:29 UTC in southwestern Germany), occurring in the form of a merrillite–apatite aggregate. However, it was not until 1975 that it was recognized as distinct from whitlockite by the International Mineralogical Association.
Occurrence Merrillite is a very important constituent of extraterrestrial rocks. It occurs in lunar rocks and in meteorites (for example, pallasites and martian meteorites). In 2022, for the first time, merrillite was found in a terrestrial environment, as an inclusion in lower-mantle diamonds from Sorriso River, Juína, Brazil.
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