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Millimetre of mercury

Millimetre of mercury is a chemistry topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand Millimetre of mercury rather than just read about it. In short: A millimetre of mercury is a manometric unit of pressure, formerly defined as the extra pressure generated by a column of mercury one millimetre high. Currently, it is defined as exactly 133.322387415 pascals, or approximately 1 torr = ⁠1/760⁠ atmosphere = ⁠101325/760⁠ pascals.

Millimetre of mercury — main illustration
Millimetre of mercury — illustration

Key takeaways

  • Millimetre of mercury belongs to chemistry; place it in that map before memorising details.
  • Learn the definition first, then one example that makes the definition concrete.
  • Connect Millimetre of mercury to a quantity you can measure, compute or draw — that is where exam questions come from.
  • Reproduce the core statement of Millimetre of mercury from memory before moving on to harder problems.

Reference excerpt

A millimetre of mercury is a manometric unit of pressure, formerly defined as the extra pressure generated by a column of mercury one millimetre high. Currently, it is defined as exactly 133.322387415 pascals, or approximately 1 torr = ⁠1/760⁠ atmosphere = ⁠101325/760⁠ pascals. It is denoted mmHg or mm Hg. Although not an SI unit, the millimetre of mercury is still often encountered in some fields; for example, it is still widely used in medicine, as demonstrated for example in the medical literature indexed in PubMed. For example, the U.S. and European guidelines on hypertension, in using millimeters of mercury for blood pressure, are reflecting the fact (common basic knowledge among health care professionals) that this is the usual unit of blood pressure in clinical medicine.

Definition The millimetre of mercury is defined as the pressure exerted by a column of mercury 1 millimetre high with a density of 13595.1 kg/m3 (approximate density at 0 °C or 32 °F) at standard gravity (9.80665 m/s2), i.e. precisely 133.322387415 pascals.

1 mmHg = 1 mm × 13595.1 kg/m3 × 9.80665 m/s2 = 133.322387415 Pa (exactly) The use of an actual column of mercury for precise measurement of pressure requires corrections for the actual gravity at given location (±0.44%) and the density of mercury at the actual temperature (−0.45% at 25 °C or 77 °F). If the top the column - the surface whose height is being measured - is exposed to some other fluid, that other fluid's temperature-dependent density must also be accounted for. A torr is a similar unit defined as exactly ⁠1/760⁠ of a standard atmosphere (1 atm = 101325 Pa), i.e. 133.322368421… pascals.

1 Torr = ⁠1/760⁠ atm = ⁠101325/760⁠ Pa = 133.322368421… Pa The torr is about one part in seven million or 0.000015% smaller than the millimetre of mercury; such difference is negligible for most practical uses. Each millimetre of mercury can be divided into 1000 micrometres of mercury, denoted μmHg or simply microns.

History

For much of human history, the pressure of gases like air was ignored, denied, or taken for granted, but as early as the 6th century BC, Greek philosopher Anaximenes of Miletus claimed that all things are made of air that is simply changed by varying levels of pressure. He could observe water evaporating, changing to a gas, and felt that this applied even to solid matter. More condensed air made colder, heavier objects, and expanded air made lighter, hotter objects. This was akin to how gases become less dense when warmer and more dense when cooler. In the 17th century, Evangelista Torricelli conducted experiments with mercury that allowed him to measure the presence of air. He would dip a glass tube, closed at one end, into a bowl of mercury and raise the closed end up out of it, keeping the open end submerged. The weight of the mercury would pull it down, leaving a partial vacuum at the far end. This validated his belief that air/gas has mass, creating pressure on things around it. Previously, the more popular conclusion, even for Galileo, was that air was weightless and it is vacuum that provided force, as in a siphon. The discovery helped bring Torricelli to the conclusion:

We live submerged at the bottom of an ocean of the element air, which by unquestioned experiments is known to have weight. This test, known as Torricelli's experiment, was essentially the first documented pressure gauge. Blaise Pascal went farther, having his brother-in-law try the experiment at different altitudes on a mountain, and finding indeed that the farther down in the ocean of atmosphere, the higher the pressure. Mercury manometers were the first accurate pressure gauges. They are less used today due to mercury's toxicity, the mercury column's sensitivity to temperature and local gravity, and the greater convenience of other instrumentation. They displayed the pressure difference between two fluids as a vertical difference between the mercury levels in two connected reservoirs. An actual mercury column reading may be converted to more fundamental units of pressure by multiplying the difference in height between two mercury levels by the density of mercury and the local gravitational acceleration. Because the specific weight of mercury depends on temperature and surface gravity, both of which vary with local conditions, specific standard values for these two parameters were adopted. This resulted in defining a "millimetre of mercury" as the pressure exerted at the base of a column of mercury 1 millimetre high with a precise density of 13595.1 kg/m3 when the acceleration due to gravity is exactly 9.80665 m/s2.

Use in medicine and physiology In medicine, pressure is still generally measured in millimetres of mercury. These measurements are in general given relative to the current atmospheric pressure: for example, a blood pressure of 120 mmHg, when the current atmospheric pressure is 760 mmHg, means 880 mmHg relative to perfect vacuum. Routine pressure measurements in medicine include:

Blood pressure, measured with a sphygmomanometer Intraocular pressure, with a tonometer Cerebrospinal fluid pressure Intracranial pressure Intramuscular pressure (compartment syndrome) Central venous pressure Pulmonary artery catheterization Mechanical ventilation In physiology manometric units are used to measure Starling forces.

See also Bar (unit) Centimetre or millimetre of water Inch of mercury Inch of water Pound per square inch Torr

Notes

References

Illustrations

Millimetre of mercury: Mercury barometer
Mercury barometer

Worked examples

Example 1 — a first encounter with Millimetre of mercury

Start with the simplest possible case. Write down what Millimetre of mercury claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In chemistry, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to Millimetre of mercury before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about Millimetre of mercury ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of Millimetre of mercury

In research
Millimetre of mercury appears in chemistry research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry
Engineering practice reuses Millimetre of mercury in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom
Millimetre of mercury is common in secondary-school and first-year university syllabi. It links to neighbouring topics Mercury (element), Units of pressure, so understanding it makes those chapters shorter.
In everyday life
Look for Millimetre of mercury outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.
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How to study Millimetre of mercury in 20 minutes

  1. Read the reference excerpt below once, without taking notes.
  2. Close the page and write down what Millimetre of mercury means in your own words.
  3. Compare your version with the excerpt and mark what you missed.
  4. Work through the three examples above with pen and paper.
  5. Explain Millimetre of mercury out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is Millimetre of mercury in simple terms?

A millimetre of mercury is a manometric unit of pressure, formerly defined as the extra pressure generated by a column of mercury one millimetre high. Currently, it is defined as exactly 133.322387415 pascals, or approximately 1 torr = ⁠1/760⁠ atmosphere = ⁠101325/760⁠ pascals.

Why does Millimetre of mercury matter?

Because it connects several chemistry ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study Millimetre of mercury?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on Millimetre of mercury.

Tags

  • Mercury (element)
  • Units of pressure

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