Mixture fraction ( Z {\displaystyle Z} ) is a quantity used in combustion studies that measures the mass fraction of one stream of a mixture formed by two feed streams, one the fuel stream and the other the oxidizer stream. Both the feed streams are allowed to have inert gases. The mixture fraction definition is usually normalized such that it approaches unity in the fuel stream and zero in the oxidizer stream. The mixture-fraction variable is commonly used as a replacement for the physical coordinate normal to the flame surface, in nonpremixed combustion.
Definition Assume a two-stream problem having one portion of the boundary the fuel stream with fuel mass fraction Y F = Y F , F {\displaystyle Y_{F}=Y_{F,F}} and another portion of the boundary the oxidizer stream with oxidizer mass fraction Y O = Y O , O {\displaystyle Y_{O}=Y_{O,O}} . For example, if the oxidizer stream is air and the fuel stream contains only the fuel, then Y O , O = 0.232 {\displaystyle Y_{O,O}=0.232} and Y F , F = 1 {\displaystyle Y_{F,F}=1} . In addition, assume there is no oxygen in the fuel stream and there is no fuel in the oxidizer stream. Let s {\displaystyle s} be the mass of oxygen required to burn unit mass of fuel (for hydrogen gas, s = 8 {\displaystyle s=8} and for C m H n {\displaystyle \mathrm {C} _{m}\mathrm {H} _{n}} alkanes, s = 32 ( m + n / 4 ) / ( 12 m + n ) {\displaystyle s=32(m+n/4)/(12m+n)} ). Introduce the scaled mass fractions as y F = Y F / Y F , F {\displaystyle y_{F}=Y_{F}/Y_{F,F}} and y O = Y O / Y O , O {\displaystyle y_{O}=Y_{O}/Y_{O,O}} . Then the mixture fraction is defined as
Z = S y F − y O + 1 S + 1 {\displaystyle Z={\frac {Sy_{F}-y_{O}+1}{S+1}}}
where
S = s Y F , F Y O , O {\displaystyle S={\frac {sY_{F,F}}{Y_{O,O}}}}
is the stoichiometry parameter, also known as the overall equivalence ratio. On the fuel-stream boundary, y F = 1 {\displaystyle y_{F}=1} and y O = 0 {\displaystyle y_{O}=0} since there is no oxygen in the fuel stream, and hence Z = 1 {\displaystyle Z=1} . Similarly, on the oxidizer-stream boundary, y F = 0 {\displaystyle y_{F}=0} and y O = 1 {\displaystyle y_{O}=1} so that Z = 0 {\displaystyle Z=0} . Anywhere else in the mixing domain, 0 < Z < 1 {\displaystyle 0<Z<1} . The mixture fraction is a function of both the spatial coordinates x {\displaystyle \mathbf {x} } and the time t {\displaystyle t} , i.e., Z = Z ( x , t ) . {\displaystyle Z=Z(\mathbf {x} ,t).}
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