chemistry

Molecular wire

Molecular wire is a chemistry topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand Molecular wire rather than just read about it. In short: Molecular wires (or sometimes called molecular nanowires) are molecular chains that conduct electric current. They are the proposed building blocks for molecular electronic devices.

Key takeaways

Molecular wire belongs to chemistry; place it in that map before memorising details.
Learn the definition first, then one example that makes the definition concrete.
Connect Molecular wire to a quantity you can measure, compute or draw — that is where exam questions come from.
Reproduce the core statement of Molecular wire from memory before moving on to harder problems.

Reference excerpt

Molecular wires (or sometimes called molecular nanowires) are molecular chains that conduct electric current. They are the proposed building blocks for molecular electronic devices. Their typical diameters are less than three nanometers, while their lengths may be macroscopic, extending to centimeters or more.

Examples Most types of molecular wires are derived from organic molecules. One naturally occurring molecular wire is DNA. Prominent inorganic examples include polymeric materials such as Li2Mo6Se6 and Mo6S9−xIx, [Pd4(CO)4(OAc)4Pd(acac)2], and single-molecule extended metal atom chains (EMACs) which comprise strings of transition metal atoms directly bonded to each other. Molecular wires containing paramagnetic inorganic moieties can exhibit Kondo peaks.

Conduction of electrons Molecular wires conduct electricity. They typically have non-linear current-voltage characteristics, and do not behave as simple ohmic conductors. The conductance follows typical power law behavior as a function of temperature or electric field, whichever is the greater, arising from their strong one-dimensional character. Numerous theoretical ideas have been used in an attempt to understand the conductivity of one-dimensional systems, where strong interactions between electrons lead to departures from normal metallic (Fermi liquid) behavior. Important concepts are those introduced by Tomonaga, Luttinger and Wigner. Effects caused by classical Coulomb repulsion (called Coulomb blockade), interactions with vibrational degrees of freedom (called phonons) and Quantum Decoherence have also been found to be important in determining the properties of molecular wires.

Synthesis Methods have been developed for the synthesis of diverse types of molecular wires (e.g. organic molecular wires and inorganic molecular wires). The basic principle is to assemble repeating modules. Organic molecular wires are usually synthesized via transition metal-mediated cross-coupling reactions.

Organic molecular wires Organic molecular wires usually consist aromatic rings connected by ethylene group or acetylene groups. Transition metal-mediated cross-coupling reactions are used to connect simple building blocks together in a convergent fashion to build organic molecular wires. For example, a simple oligo (phenylene ethylnylene) type molecular wire (B) was synthesized starting from readily available 1-bromo-4-iodobenzene (A). The final product was obtained through several steps of Sonogashira coupling reactions.

Other organic molecular wires include carbon nanotubes and DNA. Carbon nanotubes can be synthesized via various nano-technological approaches. DNA can be prepared by either step-wise DNA synthesis on solid-phase or by DNA-polymerase-catalyzed replication inside cells. It was recently shown that pyridine and pyridine-derived polymers can form electronically conductive polyazaacetylene chains under simple ultraviolet irradiation, and that the common observation of "browning" of aged pyridine samples is due in part to the formation of molecular wires. The gels exhibited a transition between ionic conductivity and electronic conductivity on irradiation.

Inorganic molecular wires One class of inorganic molecular wires consist of subunits related to Chevrel clusters. The synthesis of Mo6S9−xIx was performed in sealed and vacuumed quartz ampoule at 1343 K. In Mo6S9−xIx, the repeat units are Mo6S9−xIx clusters, which are joined together by flexible sulfur or iodine bridges. Chains can also be produced from metallo-organic precursors.

Nanowires in molecular electronics To be of use for connecting molecules, MWs need to self-assemble following well-defined routes and form reliable electrical contacts between them. To reproducibly self-assemble a complex circuit based on single molecules. Ideally, they would connect to diverse materials, such as gold metal surfaces (for connections to outside world), biomolecules (for nanosensors, nanoelectrodes, molecular switches) and most importantly, they must allow branching. The connectors should also be available of pre-determined diameter and length. They should also have covalent bonding to ensure reproducible transport and contact properties. DNA-like molecules have specific molecular-scale recognition and can be used in molecular scaffold fabrication. Complex shapes have been demonstrated, but unfortunately metal coated DNA which is electrically conducting is too thick to connect to individual molecules. Thinner coated DNA lacks electronic connectivity and is unsuited for connecting molecular electronics components. Some varieties of carbon nanotubes (CNTs) are conducting, and connectivity at their ends can be achieved by attachment of connecting groups. Unfortunately manufacturing CNTs with pre-determined properties is impossible at present, and the functionalized ends are typically not conducting, limiting their usefulness as molecular connectors. Individual CNTs can be soldered in an electron microscope, but the contact is not covalent and cannot be self-assembled. Possible routes for the construction of larger functional circuits using Mo6S9−xIx MWs have been demonstrated, either via gold nanoparticles as linkers, or by direct connection to thiolated molecules. The two approaches may lead to different possible applications. The use of GNPs offers the possibility of branching and construction of larger circuits.

Other research Molecular wires can be incorporated into polymers, enhancing their mechanical and/or conducting properties. The enhancement of these properties relies on uniform dispersion of the wires into the host polymer. MoSI wires have been made in such composites, relying on their superior solubility within the polymer host compared to other nanowires or nanotubes. Bundles of wires can be used to enhance tribological properties of polymers, with applications in actuators and potentiometers. It has been recently proposed that twisted nanowires could work as electromechanical nanodevices (or torsion nanobalances) to measure forces and torques at nanoscale with great precision.

References

External links Molybdenum sulfide MSDS

Illustrations

Molecular wire: Synthesis of a simple organic molecular wire. — Synthesis of a simple organic molecular wire.

Worked examples

Example 1 — a first encounter with Molecular wire

Start with the simplest possible case. Write down what Molecular wire claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In chemistry, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to Molecular wire before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about Molecular wire ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of Molecular wire

In research: Molecular wire appears in chemistry research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry: Engineering practice reuses Molecular wire in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom: Molecular wire is common in secondary-school and first-year university syllabi. It links to neighbouring topics Molybdenum compounds, Nanoelectronics, Pyridines, so understanding it makes those chapters shorter.
In everyday life: Look for Molecular wire outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.

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How to study Molecular wire in 20 minutes

Read the reference excerpt below once, without taking notes.
Close the page and write down what Molecular wire means in your own words.
Compare your version with the excerpt and mark what you missed.
Work through the three examples above with pen and paper.
Explain Molecular wire out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is Molecular wire in simple terms?

Molecular wires (or sometimes called molecular nanowires) are molecular chains that conduct electric current. They are the proposed building blocks for molecular electronic devices.

Why does Molecular wire matter?

Because it connects several chemistry ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study Molecular wire?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on Molecular wire.