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Molybdenite

Molybdenite is a earth science topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand Molybdenite rather than just read about it. In short: Molybdenite is a mineral of molybdenum disulfide, MoS2. Similar in appearance and feel to graphite, molybdenite has a lubricating effect that is a consequence of its layered structure.

Molybdenite — main illustration
Molybdenite — illustration

Key takeaways

  • Molybdenite belongs to earth science; place it in that map before memorising details.
  • Learn the definition first, then one example that makes the definition concrete.
  • Connect Molybdenite to a quantity you can measure, compute or draw — that is where exam questions come from.
  • Reproduce the core statement of Molybdenite from memory before moving on to harder problems.

Reference excerpt

Molybdenite is a mineral of molybdenum disulfide, MoS2. Similar in appearance and feel to graphite, molybdenite has a lubricating effect that is a consequence of its layered structure. The atomic structure consists of a sheet of molybdenum atoms sandwiched between sheets of sulfur atoms. The Mo-S bonds are strong, but the interaction between the sulfur atoms at the top and bottom of separate sandwich-like tri-layers is weak, resulting in easy slippage as well as cleavage planes. Molybdenite crystallizes in the hexagonal crystal system as the common polytype 2H and also in the trigonal system as the 3R polytype.

Description

Occurrence

Molybdenite occurs in high temperature hydrothermal ore deposits. Its associated minerals include pyrite, chalcopyrite, quartz, anhydrite, fluorite, and scheelite. Important deposits include the disseminated porphyry molybdenum deposits at Questa, New Mexico and the Henderson and Climax mines in Colorado. Molybdenite also occurs in porphyry copper deposits of Arizona, Utah, and Mexico.

The element rhenium is always present in molybdenite as a substitute for molybdenum, usually in the parts per million (ppm) range, but often up to 1–2 %. High rhenium content results in a structural variety detectable by X-ray diffraction techniques. Molybdenite ores are essentially the only source for rhenium. The presence of the radioactive isotope rhenium-187 and its daughter isotope osmium-187 provides a useful geochronologic dating technique.

Features

Molybdenite is extremely soft with a metallic luster, and is superficially almost identical to graphite, to the point where it is not possible to positively distinguish between the two minerals without scientific equipment. It marks paper in much the same way as graphite. Its distinguishing feature from graphite is its higher specific gravity, as well as its tendency to occur in a matrix.

Uses Molybdenite is an important ore of molybdenum, and is the most common source of the metal. While molybdenum is rare in the Earth's crust, molybdenite is relatively common and easy to process, and accounts for much of the metal's economic viability. Molybdenite is purified by froth flotation, and then oxidized to form soluble molybdate. Reduction of ammonium molybdate yields pure molybdenum metal, which is used for fertilizer, as a catalyst, and in battery electrodes. By far the most common use of molybdenum is as an alloy with iron. Ferromolybdenum is an important component of high strength and corrosion-resistant steel.

Semiconductor Multilayer molybdenite flakes are semiconductors with an indirect bandgap. In contrast, monolayer flakes have a direct gap. In the early years of the 20th century, molybdenite was used in some of the first crude semiconductor diodes, called cat's whisker detectors, which served as a demodulator in early crystal radios. Monolayer molybdenite shows good charge carrier mobility and can be used to create small or low-voltage transistors. The transistors can detect and emit light and may have future use in optoelectronics.

See also Powellite (calcium molybdate: CaMoO4) Rheniite (rhenium sulfide: ReS2) Wulfenite (lead molybdate: PbMoO4)

References

External links Media related to Molybdenite at Wikimedia Commons

Illustrations

Molybdenite illustration
Molybdenite: A less pure sample of molybdenite mineral
A less pure sample of molybdenite mineral
Molybdenite: Molybdenite under normal and polarized light
Molybdenite under normal and polarized light
Molybdenite: Crystal structure of molybdenite
Crystal structure of molybdenite

Worked examples

Example 1 — a first encounter with Molybdenite

Start with the simplest possible case. Write down what Molybdenite claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In earth science, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to Molybdenite before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about Molybdenite ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of Molybdenite

In research
Molybdenite appears in earth science research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry
Engineering practice reuses Molybdenite in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom
Molybdenite is common in secondary-school and first-year university syllabi. It links to neighbouring topics Dry lubricants, Glances, Hexagonal minerals, so understanding it makes those chapters shorter.
In everyday life
Look for Molybdenite outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.
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How to study Molybdenite in 20 minutes

  1. Read the reference excerpt below once, without taking notes.
  2. Close the page and write down what Molybdenite means in your own words.
  3. Compare your version with the excerpt and mark what you missed.
  4. Work through the three examples above with pen and paper.
  5. Explain Molybdenite out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is Molybdenite in simple terms?

Molybdenite is a mineral of molybdenum disulfide, MoS2. Similar in appearance and feel to graphite, molybdenite has a lubricating effect that is a consequence of its layered structure.

Why does Molybdenite matter?

Because it connects several earth science ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study Molybdenite?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on Molybdenite.

Tags

  • Dry lubricants
  • Glances
  • Hexagonal minerals
  • Minerals in space group 160
  • Minerals in space group 194
  • Molybdenum(IV) compounds
  • Molybdenum minerals
  • Non-petroleum based lubricants
  • Semiconductor materials
  • Sulfide minerals
  • Trigonal minerals

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