Hydrogen phosphate or monohydrogen phosphate (systematic name) is the inorganic ion with the formula [HPO4]2-. Its formula can also be written as [PO3(OH)]2-. Together with dihydrogen phosphate, hydrogenphosphate occurs widely in natural systems. Their salts are used in fertilizers and in cooking. Most hydrogenphosphate salts are colorless, water soluble, and nontoxic. It is a conjugate acid of phosphate [PO4]3- and a conjugate base of dihydrogen phosphate [H2PO4]−. It is formed when a pyrophosphate anion [P2O7]4− reacts with water H2O by hydrolysis, which can give hydrogenphosphate:
[P2O7]4− + H2O ⇌ 2 [HPO4]2−
Acid-base equilibria Hydrogenphosphate is an intermediate in the multistep conversion of phosphoric acid to phosphate:
Examples Diammonium phosphate, (NH4)2HPO4 Disodium phosphate, Na2HPO4, with varying amounts of water of hydration
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