The Mott–Bethe formula is an approximation used to calculate atomic electron scattering form factors, f e ( q , Z ) {\displaystyle f_{\text{e}}(q,Z)} , from atomic X-ray scattering form factors, f x ( q , Z ) {\displaystyle f_{x}(q,Z)} . The formula was derived independently by Hans Bethe and Neville Mott both in 1930, and simply follows from applying the first Born approximation for the scattering of electrons via the Coulomb interaction together with the Poisson equation for the charge density of an atom (including both the nucleus and electron cloud) in the Fourier domain. Following the first Born approximation,
f e ( q , Z ) = m e 2 32 π 3 ℏ 2 ϵ 0 ( Z − f x ( q , Z ) q 2 ) = 1 8 π 2 a 0 ( Z − f x ( q , Z ) q 2 ) ≈ ( 0.2393 nm − 1 ) ⋅ ( Z − f x ( q , Z ) q 2 ) {\displaystyle f_{\text{e}}(q,Z)={\frac {me^{2}}{32\pi ^{3}\hbar ^{2}\epsilon _{0}}}{\Bigg (}{\frac {Z-f_{x}(q,Z)}{q^{2}}}{\Bigg )}={\frac {1}{8\pi ^{2}a_{0}}}{\Bigg (}{\frac {Z-f_{x}(q,Z)}{q^{2}}}{\Bigg )}\approx (0.2393~{\textrm {nm}}^{-1})\cdot {\Bigg (}{\frac {Z-f_{x}(q,Z)}{q^{2}}}{\Bigg )}}
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