Neodymium(III) bromide is an inorganic salt of bromine and neodymium the formula NdBr3. The anhydrous compound is an off-white to pale green solid at room temperature, with an orthorhombic PuBr3-type crystal structure. The material is hygroscopic and forms a hexahydrate in water (NdBr3· 6H2O), similar to the related neodymium(III) chloride.
Preparation The direct reaction of neodymium with bromine can create neodymium(III) bromide:
2Nd + 3Br2 → 2NdBr3 In the presence of carbon, neodymium(III) oxide reacts with carbon tetrabromide to produce neodymium(III) bromide.
Structure Neodymium(III) bromide adopts the plutonium(III) bromide crystal structure. The neodymium ions are 8-coordinate and adopt a bicapped trigonal prismatic geometry. The neodymium–bromine bond lengths are 3.07 Å and 3.09 Å.
See also Lanthanide tribromide
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