Ononitol is an organic compound with the formula (CHOH)5(CHOCH3). It is derivative of inositol, specifically 4-O-methyl-myo-inositol: an ether that can be described as the result of replacing the hydroxyl (–OH) in position 4 of myo-inositol by a methoxy group. This compound occurs in several organisms. It is one of the predominant soluble carbohydrate derivatives in the root nodules of the pea plant created by the bacterium Rhizobium leguminosarum, and a constituent of Medicago sativa.
Biosynthesis The enzyme inositol 4-methyltransferase, which has been characterised from Mesembryanthemum crystallinum and Vigna umbellata, catalyses a methylation reaction in which inositol (myo-inositol) is converted to ononitol. The methyl group comes from the cofactor, S-adenosyl methionine (SAM).
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