The orbital Rashba effect refers to the emergence of finite orbital angular momentum (OAM) Bloch states at solid surfaces, driven by the confining electric field that breaks inversion symmetry. The formation of chiral OAM states is the primary energy-lowering mechanism of Rashba states. In turn, chiral spin angular momentum (SAM) arises from these preexisting chiral OAM structures through spin–orbit coupling, linking the orientations of the two angular momenta. Thus, the OAM structure plays the central role in Rashba phenomena, while the spin texture appears as a concomitant effect. The orbital Rashba effect has been observed on the surfaces of a wide range of materials, including Au, Bi, Sb, Al, and the topological insulator Bi2Se3.
Theory The formation of chiral OAM can be demonstrated with a tight-binding Hamiltonian of electrons with p x {\displaystyle p_{x}} , p y {\displaystyle p_{y}} , p z {\displaystyle p_{z}} orbitals. In the presence of electric field perpendicular to the plane (assumed along the z {\displaystyle z} -direction), hybridization between ( p x {\displaystyle p_{x}} , p y {\displaystyle p_{y}} ) orbitals and p z {\displaystyle p_{z}} orbital can take place and the Bloch states can be constructed accordingly. The Bloch state | k ⟩ {\displaystyle |{\bf {k}}\rangle } carries an internal angular orientation given by the average of the orbital angular momentum L {\displaystyle {\bf {L}}} , L k = ⟨ k | L | k ⟩ {\displaystyle {\bf {L}}_{\bf {k}}=\langle {\bf {k}}|{\bf {L}}|{\bf {k}}\rangle } . The electrostatic energy gain for the Bloch state can be expressed as
Δ E k = α O R z ^ ⋅ ( k × L k ) {\displaystyle \Delta E_{\bf {k}}=\alpha _{\rm {OR}}{\hat {z}}\cdot ({\bf {k}}\times {\bf {L}}_{\bf {k}})}
in the vicinity of the Γ {\displaystyle \Gamma } ( k = 0 {\displaystyle {\bf {k}}={\bf {0}}} ) point. It is analogous to the Rashba Hamiltonian for spins, with the SAM replaced by OAM. The coefficient α O R {\displaystyle \alpha _{\rm {OR}}} is proportional to the work function, reflecting the electrostatic confinement at the surface. To minimize Coulomb energy, the angular momentum (including both spin and orbital parts) must be perpendicular both to k {\displaystyle {\bf {k}}} and the surface normal:
L k ∝ z ^ × k . {\displaystyle {\bf {L}}_{\bf {k}}\propto {\hat {z}}\times {\bf {k}}.}
In contrast to the conventional Rashba state showing spin polarization
S k ∝ z ^ × k ( S k = ⟨ k | S | k ⟩ ) {\displaystyle {\bf {S}}_{\bf {k}}\propto {\hat {z}}\times {\bf {k}}~~({\bf {S}}_{\bf {k}}=\langle {\bf {k}}|{\bf {S}}|{\bf {k}}\rangle )}
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