Osmium(V) chloride is an inorganic chemical compound of osmium metal and chlorine with the chemical formula OsCl5.
Potential synthesis Osmium(V) chloride can be obtained in small amounts by reacting osmium hexafluoride with excess boron trichloride:
2OsF6 + 4BCl3 → 2OsCl5 + 4BF3 + Cl2 It can also be obtained by the action of sulfur dichloride on osmium tetroxide:
2OsO4 + 8SCl2 + 5Cl2 → 2OsCl5 + 8SOCl2
Physical properties Osmium(V) chloride forms a black dimeric solid, isomorphic with rhenium(V) chloride. OsCl5 is sparingly soluble in non-polar solvents. It is soluble in POCl3 to form a red-brown solution, which can crystallize OsCl5·POCl3.
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