Osmium pentafluoride is an inorganic compound with the formula OsF5. It is a blue-green solid. Like the pentafluorides of Ru, Rh, and Ir, OsF5 exists as a tetramer in the solid state.
Preparation Osmium pentafluoride can be prepared by reduction of osmium hexafluoride with iodine as a solution in iodine pentafluoride:
10 OsF6 + I2 → 10 OsF5 + 2 IF5 It can also be prepared by treating a solution of osmium hexafluoride in anhydrous hydrogen fluoride with hydrogen or silicon. Platinum gauze or UV irradiation increase the reaction rate.
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