Osmyl tetra-ammine chloride (also known as osmyl tetramminochloride and tetraamminedioxoosmium (VI) chloride) is an inorganic chemical compound with the formula [OsO2(NH3)4]Cl2.
Synthesis Osmyl tetra-ammine chloride can be prepared by adding ammonium chloride to a solution of potassium osmate.
K2[OsO2(OH)4] + 4NH4Cl → [OsO2(NH3)4]Cl2 + 2KCl + 4H2O
Properties Osmyl tetra-ammine chloride is prone to decomposition. In boiling water it disproportionates to osmium tetroxide and osmium oxydiammine chloride. When calcined in hydrogen, it yields osmium metal sponge. Despite its low solubility in water, solutions of the tetra-ammine chloride react with potassium ferrocyanide to produce a violet color.
Uses Osmyl tetra-ammine chloride was used to recover metallic osmium. However, this application was abandoned in favor of ammonium hexachloroosmate(IV) due to unsatisfactory yields. Despite this, it is still readily available to purchase from some chemical suppliers.
Related compounds Other osmyl tetra-ammine salts are known, such as the sulfate, nitrate, and oxalate. Their syntheses and characteristics are similar to those of the chloride. Their parent base, osmyl tetra-ammine hydroxide, is unstable and known only in solution.
References



