A carbide oxide or oxycarbide is a mixed anion compound that contains oxide O2− and carbon containing anions. These compounds are distinct from carbonates, carbonites, or carbonyls, which have covalent bonds between carbon and oxygen.
Properties Many oxycarbides can have a range of compositions with substitution of some carbon by oxygen, or vice-versa. For example with zirconium there are carbide oxides with formulas in the range ZrCxO2(1-x), varying from ZrC to ZrO2. But also there are others more zirconium rich with formulas ZrCxOy where x + y ≤ 1.
Use Oxycarbides are investigated for their catalytic activity. They can catalyse formation of hydrocarbons from hydrogen and carbon monoxide, or to form benzene and hydrogen from methane, or to form hydrogen from organic substances. They are also important in metallurgy, as an intermediate product when carbon is used to reduce metal oxides. When hot metallic carbides are exposed to oxygen they can also form oxycarbides. Because of their hardness and high melting point, they are difficult to analyse. Since rare earth oxycarbides are electrically conductive, they can be used as electrodes in the electrochemical production of metals. Titanium oxycarbide has been investigated as a fuel cell electrode.
Production Oxycarbides may be produced by an incomplete reaction of a metal oxide with carbon.Metal carbides can oxidise at high temperature with the addition of oxygen, yielding an oxycarbide, and carbon monoxide. Less common methods of production are electrochemical, reduction by methane, heating a metal organic framework, or decomposing a metal carbonyl compound.
Related Related compounds include oxycarbonitride.
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"?" in formula means ratio of elements unspecified.
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