Palladium disulfide is a chemical compound of palladium and sulfur with the chemical formula PdS2.
Structure PdS2 contains sulfur-sulfur bonds so it can be thought of as a disulfide that formally consists of S22− and Pd2+ ions, instead of S2− and Pd4+ ions. It adopts a layered crystal structure that contains square planar palladium centres and trigonal pyramidal sulfur centres.
Preparation Palladium disulfide is formed when palladium(II) sulfide is heated with an excess of sulfur.
PdS + S → PdS2 However, some starting material may remain even after heating for many months. An alternative route involves heating palladium(II) chloride and excess sulfur to 450 °C in a sealed tube, then washing the crude product with carbon disulfide. This procedure yields PdS2 free of PdS.
Related compounds A variety of other compounds in the Pd-S system have been reported, including Pd4S, Pd2.8S, Pd2.2S and PdS.
See also Pyrite Marcasite
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