In quantum mechanics, the case of a particle in a one-dimensional ring is similar to the particle in a box. The Schrödinger equation for a free particle which is restricted to a ring (technically, whose configuration space is the circle S 1 {\displaystyle S^{1}} ) is
− ℏ 2 2 m ∇ 2 ψ = E ψ {\displaystyle -{\frac {\hbar ^{2}}{2m}}\nabla ^{2}\psi =E\psi }
with boundary conditions
ψ ( θ + 2 π ) = ψ ( θ ) {\displaystyle \psi (\theta +2\pi )=\psi (\theta )}
expressing the fact that the particle is in a ring.
Wave function
Using polar coordinates on the 1-dimensional ring of radius R, the wave function depends only on the angular coordinate, and so
∇ 2 = 1 R 2 ∂ 2 ∂ θ 2 {\displaystyle \nabla ^{2}={\frac {1}{R^{2}}}{\frac {\partial ^{2}}{\partial \theta ^{2}}}}
Requiring that the wave function be periodic in θ {\displaystyle \ \theta } with a period 2 π {\displaystyle 2\pi } (from the demand that the wave functions be single-valued functions on the circle), and that they be normalized leads to the conditions
∫ 0 2 π | ψ ( θ ) | 2 d θ = 1 {\displaystyle \int _{0}^{2\pi }\left|\psi (\theta )\right|^{2}\,d\theta =1\ } , and
ψ ( θ ) = ψ ( θ + 2 π ) {\displaystyle \ \psi (\theta )=\ \psi (\theta +2\pi )}
Under these conditions, the solution to the Schrödinger equation is given by
ψ ± ( θ ) = 1 2 π e ± i R ℏ 2 m E θ {\displaystyle \psi _{\pm }(\theta )={\frac {1}{\sqrt {2\pi }}}\,e^{\pm i{\frac {R}{\hbar }}{\sqrt {2mE}}\,\theta }}
Energy eigenvalues The energy eigenvalues E {\displaystyle E} are quantized because of the periodic boundary conditions, and they are required to satisfy
e ± i R ℏ 2 m E θ = e ± i R ℏ 2 m E ( θ + 2 π ) {\displaystyle e^{\pm i{\frac {R}{\hbar }}{\sqrt {2mE}}\,\theta }=e^{\pm i{\frac {R}{\hbar }}{\sqrt {2mE}}(\theta +2\pi )}} or
e ± i 2 π R ℏ 2 m E = 1 = e i 2 π n {\displaystyle e^{\pm i2\pi {\frac {R}{\hbar }}{\sqrt {2mE}}}=1=e^{i2\pi n}}
The eigenfunction and eigenenergies are
ψ ( θ ) = 1 2 π e ± i n θ {\displaystyle \psi (\theta )={\frac {1}{\sqrt {2\pi }}}\,e^{\pm in\theta }}
E n = n 2 ℏ 2 2 m R 2 {\displaystyle E_{n}={\frac {n^{2}\hbar ^{2}}{2mR^{2}}}} where n = 0 , ± 1 , ± 2 , ± 3 , … {\displaystyle n=0,\pm 1,\pm 2,\pm 3,\ldots }
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