Peroxydisulfuryl difluoride is an inorganic compound from the group of peroxides. The chemical formula is F2O6S2.
Synthesis Peroxydisulfuryl difluoride can be obtained by the reaction of sulfur trioxide with fluorine in the presence of silver(II) fluoride or by electrolysis of fluorosulfuric acid.
2SO3 + F2 → S2O6F2 It is also possible to prepare it by reacting chromium(V) fluoride with sulfur trioxide:
CrF5 + 5SO3 → S2O6F2 + Cr(SO3F)3 or by the reaction between fluorosulfuric acid and dioxygenyl hexafluoroarsenate:
2HSO3F + 2[O2][AsF6] → S2O6F2 + 2O2 + 2AsF5 + 2HF
Physical properties Peroxydisulfuryl difluoride is a colorless liquid with an unpleasant odor that hydrolyzes with water to produce oxygen and fluorosulfuric acid. The compound can ignite organic materials upon contact.
Chemical properties It reacts with cesium fluorosulfonate and silver fluorosulfonate to produce the divalent silver compound CsAg(SO3F)3. Iodine(I) fluorosulfonate can be obtained from iodine and peroxydisulfuryl difluoride:
I2 + S2O6F2 → 2ISO3F
Uses Peroxydisulfuryl difluoride can be used to produce fluorosulfates. It is a strong oxidizing agent and can be used for the oxidation of noble metals (Ag Au Re Pt Os Rh) to the salts of fluorosulfuric acid.
See also Disulfuryl fluoride Disulfuryl chloride Disulfuryl chloride fluoride
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