Peroxynitric acid or peroxonitric acid is a chemical compound with the formula HNO4. It is an oxyacid of nitrogen, after peroxynitrous acid.
Preparation Peroxynitrate, the conjugate base of peroxynitric acid, is formed rapidly during decomposition of peroxynitrite in neutral conditions.
Atmospheric chemistry Peroxynitric acid is formed in the atmosphere, although it is unstable, it is important as a reservoir for NO2 through the reversible radical reaction:
HO2NO2 ⇌ HO2• + NO2•
Stability The pure compound decomposes explosively at −30 °C (−22 °F). Solutions in water or acetic acid of over 70% concentration decompose autocatalytically with resulting explosions.
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