Pertechnetyl fluoride is an inorganic compound, a salt of technetium and hydrofluoric acid with the chemical formula TcO3F. The compound was originally synthesized by H. Selig and G. Malm in 1963.
Synthesis Effect of fluorine on technetium(IV) oxide at 150 °C: 3 TcO2 + 4 F2 → 2 TcO3F + TcF6 Dissolution of ammonium pertechnetate in anhydrous hydrogen fluoride: NH4TcO4 + 2 HF → TcO3F + NH4F + H2O
Physical properties The compound forms a yellow substance.
Chemical properties The compound can be hydrolyzed to produce pertechnetic acid and hydrofluoric acid.
TcO3F + H2O → HTcO4 + HF It also reacts with arsenic pentafluoride or antimony pentafluoride.
References


