Perylenetetracarboxylic dianhydride (PTCDA) is an organic dye molecule and an organic semiconductor. It is used as a precursor to a class of molecules known as Rylene dyes, which are useful as pigments and dyes. It is a dark red solid with low solubility in aromatic solvents. The compound has attracted much interest as an organic semiconductor.
Structure PTCDA consists of a perylene core to which two anhydride groups have been attached, one at either side. It occurs in two crystalline forms, α and β. Both have the P21/c monoclinic symmetry and a density of ca. 1.7 g/cm3, which is relatively high for organic compounds. Their lattice parameters are:
Self-assembly and films
Use The main industrial use of PTCDA is as a precursor to Rylene dyes.
References


![Perylenetetracarboxylic dianhydride: Atomic force microscopy image of a single PTCDA molecule on Si at room temperature.[4]](https://upload.wikimedia.org/wikipedia/commons/thumb/e/e9/PTCDA_AFM.jpg/500px-PTCDA_AFM.jpg?utm_source=en.wikipedia.org&utm_campaign=parser&utm_content=thumbnail)
![Perylenetetracarboxylic dianhydride: Self-assembly of PTCDA molecules on NaCl, scanning tunneling microscopy image.[5]](https://upload.wikimedia.org/wikipedia/commons/thumb/e/e6/PTCDA_self-assembly_STM.jpg/330px-PTCDA_self-assembly_STM.jpg?utm_source=en.wikipedia.org&utm_campaign=parser&utm_content=thumbnail)
