Petrography is a branch of petrology that focuses on detailed descriptions of rocks. Someone who studies petrography is called a petrographer. The mineral content and the textural relationships within the rock are described in detail. The classification of rocks is based on the information acquired during the petrographic analysis. Petrographic descriptions start with the field notes at the outcrop and include macroscopic description of hand-sized specimens. The most important petrographer's tool is the petrographic microscope. The detailed analysis of minerals by optical mineralogy in thin section and the micro-texture and structure are critical to understanding the origin of the rock. Electron microprobe or atom probe tomography analysis of individual grains as well as whole rock chemical analysis by atomic absorption, X-ray fluorescence, and laser-induced breakdown spectroscopy are used in a modern petrographic lab. Individual mineral grains from a rock sample may also be analyzed by X-ray diffraction when optical means are insufficient. Analysis of microscopic fluid inclusions within mineral grains with a heating stage on a petrographic microscope provides clues to the temperature and pressure conditions existent during the mineral formation.
History Petrography as a science began in 1828 when Scottish physicist William Nicol invented the technique for producing polarized light by cutting a crystal of Iceland spar, a variety of calcite, into a special prism which became known as the Nicol prism. The addition of two such prisms to the ordinary microscope converted the instrument into a polarizing, or petrographic microscope. Using transmitted light and Nicol prisms, it was possible to determine the internal crystallographic character of very tiny mineral grains, greatly advancing the knowledge of a rock's constituents. During the 1840s, a development by Henry C. Sorby and others firmly laid the foundation of petrography. This was a technique to study very thin slices of rock. A slice of rock was affixed to a microscope slide and then ground so thin that light could be transmitted through mineral grains that otherwise appeared opaque. The position of adjoining grains was not disturbed, thus permitting analysis of rock texture. Thin section petrography became the standard method of rock study. Since textural details contribute greatly to knowledge of the sequence of crystallization of the various mineral constituents in a rock, petrography progressed into petrogenesis and ultimately into petrology. Petrography principally advanced in Germany in the latter 19th century.
Methods of investigation
Macroscopic characters The macroscopic characters of rocks, those visible in hand-specimens without the aid of the microscope, are very varied and difficult to describe accurately and fully. The geologist in the field depends principally on them and on a few rough chemical and physical tests; and to the practical engineer, architect and quarry-master they are all-important. Although frequently insufficient in themselves to determine the true nature of a rock, they usually serve for a preliminary classification, and often give all the information needed. With a small bottle of acid to test for carbonate of lime, a knife to ascertain the hardness of rocks and minerals, and a pocket lens to magnify their structure, the field geologist is rarely at a loss to what group a rock belongs. The fine grained species are often indeterminable in this way, and the minute mineral components of all rocks can usually be ascertained only by microscopic examination. But it is easy to see that a sandstone or grit consists of more or less rounded, water-worn sand grains and if it contains dull, weathered particles of feldspar, shining scales of mica or small crystals of calcite these also rarely escape observation. Shales and clay rocks generally are soft, fine grained, often laminated and not infrequently contain minute organisms or fragments of plants. Limestones are easily marked with a knife-blade, effervesce readily with weak cold acid and often contain entire or broken shells or other fossils. The crystalline nature of a granite or basalt is obvious at a glance, and while the former contains white or pink feldspar, clear vitreous quartz and glancing flakes of mica, the other shows yellow-green olivine, black augite, and gray stratiated plagioclase. Other simple tools include the blowpipe (to test the fusibility of detached crystals), the goniometer, the magnet, the magnifying glass and the specific gravity balance.
Microscopic characteristics
When dealing with unfamiliar types or with rocks so fine grained that their component minerals cannot be determined with the aid of a hand lens, a microscope is used. Characteristics observed under the microscope include colour, colour variation under plane polarised light (pleochroism, produced by the lower Nicol prism, or more recently polarising films), fracture characteristics of the grains, refractive index (in comparison to the mounting adhesive, typically Canada balsam), and optical symmetry (birefringent or isotropic). In toto, these characteristics are sufficient to identify the mineral, and often to quite tightly estimate its major element composition. The process of identifying minerals under the microscope is fairly subtle, but also mechanistic – it would be possible to develop an identification key that would allow a computer to do it. Recently, the field of digital petrography has been developing, including through the use of artificial intelligence technologies. The more difficult and skilful part of optical petrography is identifying the interrelationships between grains and relating them to features seen in hand-sized specimen, at outcrop, or in mapping.
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