Phosphate minerals are minerals that contain the tetrahedrally coordinated phosphate (PO3−4) anion, sometimes with arsenate (AsO3−4) and vanadate (VO3−4) substitutions, along with chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions, that also fit into the crystal structure. The phosphate class of minerals is a large and diverse group, however, only a few species are relatively common.
Applications
Phosphate rock, which contains high concentrations of apatite-group minerals, serves as the primary economic source for phosphorus extraction. The majority of mined phosphate minerals are utilized in the agricultural industry for the production of fertilizers and animal feed supplements. Beyond agriculture, these minerals are employed in industrial applications including water treatment, metallurgy, food preservation, ceramics, and cosmetics. Additionally, phosphate compounds are commonly utilized in electrochemical conversion coatings to control rust and inhibit corrosion on ferrous materials.
Examples Phosphate minerals include:
Triphylite Li(Fe,Mn)PO4 Monazite (La, Y, Nd, Sm, Gd, Ce,Th)PO4, rare earth metals Hinsdalite PbAl3(PO4)(SO4)(OH)6 Pyromorphite Pb5(PO4)3Cl Amblygonite LiAlPO4F Lazulite (Mg,Fe)Al2(PO4)2(OH)2 Wavellite Al3(PO4)2(OH)3·5H2O Turquoise CuAl6(PO4)4(OH)8·5H2O Autunite Ca(UO2)2(PO4)2·10–12H2O Phosphophyllite Zn2(Fe,Mn)(PO4)2·4H2O Struvite (NH4)MgPO4·6H2O Xenotime-Y Y(PO4) Apatite group Ca5(PO4)3(F,Cl,OH) Hydroxyapatite Ca5(PO4)3OH Fluorapatite Ca5(PO4)3F Chlorapatite Ca5(PO4)3Cl Bromapatite Mitridatite group: Arseniosiderite-mitridatite series (Ca2(Fe3+)3[(O)2|(AsO4)3]·3H2O -- Ca2(Fe3+)3[(O)2|(PO4)3]·3H2O) Arseniosiderite-robertsite series (Ca2(Fe3+)3[(O)2|(AsO4)3]·3H2O -- Ca3(Mn3+)4[(OH)3|(PO4)2]2·3H2O)
Nickel–Strunz classification -08- phosphates IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the classification of Nickel–Strunz (mindat.org, 10 ed, pending publication).
Abbreviations: "*" – discredited (IMA/CNMNC status). "?" – questionable/doubtful (IMA/CNMNC status). "REE" – Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) "PGE" – Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt) 03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V[5,6] Vanadates), 09 Silicates: Neso: insular (from Greek νησος nēsos, island) Soro: grouping (from Greek σωροῦ sōros, heap, mound (especially of corn)) Cyclo: ring Ino: chain (from Greek ις [genitive: ινος inos], fibre) Phyllo: sheet (from Greek φύλλον phyllon, leaf) Tekto: three-dimensional framework Nickel–Strunz code scheme: NN.XY.##x NN: Nickel–Strunz mineral class number X: Nickel–Strunz mineral division letter Y: Nickel–Strunz mineral family letter ##x: Nickel–Strunz mineral/group number, x add-on letter
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