Phosphoramide is a chemical compound with the molecular formula O=P(NH2)3. It is a derivative of phosphoric acid in which each of the hydroxyl groups have been replaced with an amino group. In bulk, the compound is a white solid which is soluble in polar solvents.
Chemical properties Phosphoramide arises from the reaction of phosphoryl chloride with ammonia. In moist air, it hydrolyzes to an ammonium salt:
2 H2O + O=P(NH2)3 → [NH4]+[PO2(OH)(NH2)]− + NH3 It reacts with sodium hydroxide with loss of ammonia:
NaOH + O=P(NH2)3 → Na+[PO2(NH2)2]− + NH3 The related thiophosphoryl triamide compound S=P(NH2)3 was made from the reaction of thiophosphoryl chloride with ammonia.
Phosphoramides
Phosphoramide is also the parent compound for a range of derivatives called phosphoramides. An example compound is the polar solvent hexamethylphosphoramide (HMPA).
References
External links Media related to phosphoramides at Wikimedia Commons The dictionary definition of phosphoramide at Wiktionary


