Photovoltaics (PV) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect, a phenomenon studied in physics, photochemistry, and electrochemistry. The photovoltaic effect is commercially used for electricity generation and as photosensors. A photovoltaic system employs solar modules, each comprising a number of solar cells, which generate electrical power. PV installations may be ground-mounted, rooftop-mounted, wall-mounted or floating. The mount may be fixed or use a solar tracker to follow the sun across the sky. Photovoltaic technology helps to mitigate climate change because it emits much less carbon dioxide than fossil fuels. Solar PV has specific advantages as an energy source: once installed, its operation does not generate any pollution or any greenhouse gas emissions; it shows scalability in respect of power needs and silicon has large availability in the Earth's crust, although other materials required in PV system manufacture such as silver may constrain further growth in the technology. Other major constraints identified include competition for land use. The use of PV as a main source requires energy storage systems or global distribution by high-voltage direct current power lines causing additional costs, and also has a number of other specific disadvantages such as variable power generation which have to be balanced. Production and installation does cause some pollution and greenhouse gas emissions, though only a fraction of the emissions caused by fossil fuels. Photovoltaic systems have long been used in specialized applications as stand-alone installations and grid-connected PV systems have been in use since the 1990s. Photovoltaic modules were first mass-produced in 2000, when the German government funded a one hundred thousand roof program. Decreasing costs has allowed PV to grow as an energy source. This has been partially driven by massive Chinese government investment in developing solar production capacity since 2000, and achieving economies of scale. Improvements in manufacturing technology and efficiency have also led to decreasing costs. Net metering and financial incentives, such as preferential feed-in tariffs for solar-generated electricity, have supported solar PV installations in many countries. Panel prices dropped by a factor of 4 between 2004 and 2011. Module prices dropped by about 90% over the 2010s. In 2022, worldwide installed PV capacity increased to more than 1 terawatt (TW) covering nearly two percent of global electricity demand. After hydro and wind powers, PV is the third renewable energy source in terms of global capacity. In 2022, the International Energy Agency expected a growth by over 1 TW from 2022 to 2027. In some instances, PV has offered the cheapest source of electrical power in regions with a high solar potential, with a bid for pricing as low as 0.015 US$/kWh in Qatar in 2023. In 2023, the International Energy Agency stated in its World Energy Outlook that '[f]or projects with low cost financing that tap high quality resources, solar PV is now the cheapest source of electricity in history.
Etymology The term "photovoltaic" comes from the Greek φῶς (phōs) meaning "light", and from "volt", the unit of electromotive force, the volt, which in turn comes from the last name of the Italian physicist Alessandro Volta, inventor of the battery (electrochemical cell). The term "photovoltaic" has been in use in English since 1849.
History
In 1839, the French scientist Edmond Becquerel first observed the photovoltaic effect when he noted an electric current was produced by a metallic solution exposed to solar radiation. In 1989, the German Ministry of Research and Technology initiated the first ever program to finance PV roofs. The program was led by Walter Sandtner in Bonn, Germany. In 1994, Japan followed in their footsteps and conducted a similar program with 539 residential PV systems installed. Since then, many countries have continued to produce and finance PV systems.
Solar cells
Photovoltaics are best known as a method for generating electric power by using solar cells to convert energy from the sun into a flow of electrons by the photovoltaic effect. Solar cells produce direct current electricity from sunlight which can be used to power equipment or to recharge batteries. The first practical application of photovoltaics was to power orbiting satellites and other spacecraft, but today the majority of photovoltaic modules are used for grid-connected systems for power generation. In this case an inverter is required to convert the DC to AC. There is also a smaller market for stand alone systems for remote dwellings, boats, recreational vehicles, electric cars, roadside emergency telephones, remote sensing, and cathodic protection of pipelines. Photovoltaic power generation employs solar modules composed of a number of solar cells containing a semiconductor material. Copper solar cables connect modules (module cable), arrays (array cable), and sub-fields. Because of the growing demand for renewable energy sources, the manufacturing of solar cells and photovoltaic arrays has advanced considerably in recent years. Cells require protection from the environment and are usually packaged tightly in solar modules. Photovoltaic module power is measured under standard test conditions (STC) in "Wp" (watts peak). The actual power output at a particular place may be less than or greater than this rated value, depending on geographical location, time of day, weather conditions, and other factors. Solar photovoltaic array capacity factors are typically under 25% when not coupled with storage, which is lower than many other industrial sources of electricity.
Solar cell efficiencies
Performance and degradation
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