Plagioclase ( PLAJ-(ee)-ə-klayss, PLAYJ-, -klayz) is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or "record-groove" effect. Plagioclase is a major constituent mineral in Earth's crust and is consequently an important diagnostic tool in petrology for identifying the composition, origin and evolution of igneous rocks. Plagioclase is also a major constituent of rock in the highlands of the Moon. Analysis of thermal emission spectra from the surface of Mars suggests that plagioclase is the most abundant mineral in the crust of Mars. Its name comes from Ancient Greek πλάγιος (plágios) 'oblique' and κλάσις (klásis) 'fracture', in reference to its two cleavage angles.
Properties Plagioclase is the most common and abundant mineral group in the Earth's crust. Part of the feldspar family of minerals, it is abundant in igneous and metamorphic rock, and it is also common as a detrital mineral in sedimentary rock. It is not a single mineral, but is a solid solution of two end members, albite or sodium feldspar (NaAlSi3O8) and anorthite or calcium feldspar (CaAl2Si2O8). These can be present in plagioclase in any proportion from pure anorthite to pure albite. The composition of plagioclase can thus be written as Na1−xCaxAl1+xSi3−xO8 where x ranges from 0 for pure albite to 1 for pure anorthite. This solid solution series is known as the plagioclase series. The composition of a particular sample of plagioclase is customarily expressed as the mol% of anorthite in the sample. For example, plagioclase that is 40 mol% anorthite would be described as An40 plagioclase. The ability of albite and anorthite to form solid solutions in any proportions at elevated temperature reflects the ease with which calcium and aluminium can substitute for sodium and silicon in the plagioclase crystal structure. Although a calcium ion has a charge of +2, versus +1 for a sodium ion, the two ions have very nearly the same effective radius. The difference in charge is accommodated by the coupled substitution of aluminium (charge +3) for silicon (charge +4), both of which can occupy tetrahedral sites (surrounded by four oxygen ions). This contrasts with potassium, which has the same charge as sodium, but is a significantly larger ion. As a result of the size and charge difference between potassium and calcium, there is a very wide miscibility gap between anorthite and potassium feldspar, (KAlSi3O8), the third common rock-forming feldspar end member. Potassium feldspar does form a solid solution series with albite, due to the identical charges of sodium and potassium ions, which is known as the alkali feldspar series. Thus, almost all feldspar found on Earth is either plagioclase or alkali feldspar, with the two series overlapping for pure albite. When a plagioclase composition is described by its anorthite mol% (such as An40 in the previous example) it is assumed that the remainder is albite, with only a minor component of potassium feldspar. Plagioclase of any composition shares many basic physical characteristics, while other characteristics vary smoothly with composition. The Mohs hardness of all plagioclase species is 6 to 6.5, and cleavage is perfect on [001] and good on [010], with the cleavage planes meeting at an angle of 93 to 94 degrees. It is from this slightly oblique cleavage angle that plagioclase gets its name, Ancient Greek plágios (πλάγιος 'oblique') + klásis (κλάσις 'fracture'). The name was introduced by August Breithaupt in 1847. There is also a poor cleavage on [110] rarely seen in hand samples. The luster is vitreous to pearly and the diaphaneity is transparent to translucent. The tenacity is brittle, and the fracture is uneven or conchoidal, but the fracture is rarely observed due to the strong tendency of the mineral to cleave instead. At low temperature, the crystal structure belongs to the triclinic system, space group P1 Well-formed crystals are rare and are most commonly sodic in composition. Well-shaped samples are instead typically cleavage fragments. Well-formed crystals are typically bladed or tabular parallel to [010]. Plagioclase is usually white to greyish-white in color, with a slight tendency for more calcium-rich samples to be darker. Impurities can infrequently tint the mineral greenish, yellowish, or flesh-red. Ferric iron (Fe3+) gives a pale yellow color in plagioclase feldspar from Lake County, Oregon. The specific gravity increases smoothly with calcium content, from 2.62 for pure albite to 2.76 for pure anorthite, and this can provide a useful estimate of composition if measured accurately. The index of refraction likewise varies smoothly from 1.53 to 1.58, and, if measured carefully, this also gives a useful composition estimate. Plagioclase almost universally shows a characteristic polysynthetic twinning that produces twinning striations on [010]. These striations allow plagioclase to be distinguished from alkali feldspar. Plagioclase often also displays Carlsbad, Baveno, and Manebach Law twinning.
Plagioclase series members The composition of a plagioclase feldspar is typically denoted by its overall fraction of anorthite (%An) or albite (%Ab). There are several named plagioclase feldspars that fall between albite and anorthite in the series. The following table shows their compositions in terms of constituent anorthite and albite percentages.
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