Plutonium(III) oxide is an inorganic compound of plutonium and oxygen with the chemical formula Pu2O3. This is a sesquioxide of plutonium and is a lower oxide compared to the more common plutonium dioxide PuO2.
Synthesis The cubic modification of the compound is formed by thermal dissociation of plutonium dioxide:
2PuO2 → Pu2O3 + O2 The hexagonal modification is formed during the reduction of plutonium dioxide with metallic plutonium:
2PuO2 + Pu → 2Pu2O3
Physical properties The compound forms black crystals of cubic system, space group I a3. The compound also forms crystals of hexagohal system, space group P 3m1.
Chemical properties The compound oxidizes when stored in open air:
2Pu2O3 + O2 → 4PuO2
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